La2O2MQ2 phases: Stability and synthetic challenges

IF 3.4 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Solid State Sciences Pub Date : 2024-10-09 DOI:10.1016/j.solidstatesciences.2024.107719

Glen R. Hebberd, Budhika G. Mendis, Leon Bowen, Stewart J. Clark, Emma E. McCabe

引用次数: 0

Abstract

Oxychalcogenides containing transition metal or p block cations have potential for thermoelectric, photocatalytic and magnetic applications but the synthetic pathways to these quaternary phases are not fully understood. This presents a challenge to the design and preparation of new functional materials. Our combined experimental and computational study of La₂O₂MQ₂ (M = +2 cation; Q = sulfide, selenide anion) systems explores the thermodynamic constraints on synthesis and highlights the subtle balance in stabilities of phases formed via competing reaction pathways.

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La2O2MQ2 相：稳定性与合成挑战

含有过渡金属或 p 块阳离子的氧化钙苷具有热电、光催化和磁性应用的潜力，但这些四元相的合成途径还不完全清楚。这对设计和制备新型功能材料提出了挑战。我们对 La2O2MQ2（M = +2 阳离子；Q = 硫化物、硒化阴离子）系统进行了实验和计算相结合的研究，探索了合成的热力学限制，并强调了通过相互竞争的反应途径形成的相在稳定性方面的微妙平衡。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Solid State Sciences 化学-无机化学与核化学

CiteScore

6.60

自引率

2.90%

发文量

214

审稿时长

27 days

期刊介绍： Solid State Sciences is the journal for researchers from the broad solid state chemistry and physics community. It publishes key articles on all aspects of solid state synthesis, structure-property relationships, theory and functionalities, in relation with experiments. Key topics for stand-alone papers and special issues: -Novel ways of synthesis, inorganic functional materials, including porous and glassy materials, hybrid organic-inorganic compounds and nanomaterials -Physical properties, emphasizing but not limited to the electrical, magnetical and optical features -Materials related to information technology and energy and environmental sciences. The journal publishes feature articles from experts in the field upon invitation. Solid State Sciences - your gateway to energy-related materials.