{"title":"La2O2MQ2 phases: Stability and synthetic challenges","authors":"","doi":"10.1016/j.solidstatesciences.2024.107719","DOIUrl":null,"url":null,"abstract":"<div><div>Oxychalcogenides containing transition metal or p block cations have potential for thermoelectric, photocatalytic and magnetic applications but the synthetic pathways to these quaternary phases are not fully understood. This presents a challenge to the design and preparation of new functional materials. Our combined experimental and computational study of La<sub>2</sub>O<sub>2</sub><em>MQ</em><sub>2</sub> (<em>M</em> = +2 cation; <em>Q</em> = sulfide, selenide anion) systems explores the thermodynamic constraints on synthesis and highlights the subtle balance in stabilities of phases formed via competing reaction pathways.</div></div>","PeriodicalId":432,"journal":{"name":"Solid State Sciences","volume":null,"pages":null},"PeriodicalIF":3.4000,"publicationDate":"2024-10-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Solid State Sciences","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S129325582400284X","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
Oxychalcogenides containing transition metal or p block cations have potential for thermoelectric, photocatalytic and magnetic applications but the synthetic pathways to these quaternary phases are not fully understood. This presents a challenge to the design and preparation of new functional materials. Our combined experimental and computational study of La2O2MQ2 (M = +2 cation; Q = sulfide, selenide anion) systems explores the thermodynamic constraints on synthesis and highlights the subtle balance in stabilities of phases formed via competing reaction pathways.
期刊介绍:
Solid State Sciences is the journal for researchers from the broad solid state chemistry and physics community. It publishes key articles on all aspects of solid state synthesis, structure-property relationships, theory and functionalities, in relation with experiments.
Key topics for stand-alone papers and special issues:
-Novel ways of synthesis, inorganic functional materials, including porous and glassy materials, hybrid organic-inorganic compounds and nanomaterials
-Physical properties, emphasizing but not limited to the electrical, magnetical and optical features
-Materials related to information technology and energy and environmental sciences.
The journal publishes feature articles from experts in the field upon invitation.
Solid State Sciences - your gateway to energy-related materials.