Microwave-induced alterations in the structure of coals at different metamorphic stages

Abstract

Despite the global trend toward decarbonization, coal continues to play a significant role in energy production, as current renewable energy sources cannot fully meet the increasing global energy demand. The main objective of decarbonization is to reduce greenhouse gas emissions, especially carbon dioxide. Enhancing coal usage efficiency can help decrease these emissions. Electromagnetic activation of bituminous coal is already employed for dehydration, ash removal, desulfurization, and improving the grinding process of raw coal. This research aims to study the specifics of coal electromagnetic activation using microwave radiation and its effects on the physical and chemical processes occurring in coals at different metamorphic stages. The results suggest that this electromagnetic treatment leads to the destruction of hydroxyl groups and the formation of free hydrogen. Coals at higher metamorphic stages heat up faster due to their higher structural density. Coals at lower metamorphic stages take longer to heat up and require more processing time to be effective, while lower power levels are necessary to avoid mechanical breakdown. Activation time and coal particle size are significant factors; their optimal combination provides the maximum effect. These findings contribute to optimizing microwave treatment parameters for different coal types, potentially enhancing coal utilization efficiency and reducing environmental impact.