Structural and synthesis study of eight isostructural coordination polymers formed by 5-sulfoisophthalic acid and lanthanide ions

IF 2.4 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Polyhedron Pub Date : 2024-09-28 DOI:10.1016/j.poly.2024.117243

Anna Luiza Cravinho Varella, Gabriel Brite Vieira, Filipe Barra de Almeida

{"title":"Structural and synthesis study of eight isostructural coordination polymers formed by 5-sulfoisophthalic acid and lanthanide ions","authors":"Anna Luiza Cravinho Varella, Gabriel Brite Vieira, Filipe Barra de Almeida","doi":"10.1016/j.poly.2024.117243","DOIUrl":null,"url":null,"abstract":"<div><div>This work presents the synthesis and structural characterization of eight isostructural 1D coordination polymers formed by the coordination of 5-sulfoisophthalic acid with various lanthanides ions: Ln = <span><math><mrow><mi>C</mi><mi>e</mi><mrow><mfenced><mrow><mi>I</mi><mi>I</mi><mi>I</mi></mrow></mfenced></mrow><mo>,</mo><mspace></mspace><mi>Pr</mi><mrow><mfenced><mrow><mi>I</mi><mi>I</mi><mi>I</mi></mrow></mfenced></mrow><mo>,</mo><mspace></mspace><mi>S</mi><mi>m</mi><mrow><mfenced><mrow><mi>I</mi><mi>I</mi><mi>I</mi></mrow></mfenced></mrow><mo>,</mo><mspace></mspace><mi>G</mi><mi>d</mi><mrow><mfenced><mrow><mi>I</mi><mi>I</mi><mi>I</mi></mrow></mfenced></mrow><mo>,</mo><mspace></mspace><mi>D</mi><mi>y</mi><mrow><mfenced><mrow><mi>I</mi><mi>I</mi><mi>I</mi></mrow></mfenced></mrow><mo>,</mo></mrow></math></span> <span><math><mrow><mi>H</mi><mi>o</mi><mrow><mfenced><mrow><mi>I</mi><mi>I</mi><mi>I</mi></mrow></mfenced></mrow><mo>,</mo><mspace></mspace><mi>E</mi><mi>r</mi><mrow><mo>(</mo><mi>I</mi><mi>I</mi><mi>I</mi><mo>)</mo><mspace></mspace></mrow><mi>a</mi><mi>n</mi><mi>d</mi><mspace></mspace><mi>T</mi><mi>m</mi><mrow><mo>(</mo><mi>I</mi><mi>I</mi><mi>I</mi><mo>)</mo></mrow></mrow></math></span>. The structures were synthetized via a two-step process, wherein a solution of lanthanide ions was added to a mixture of 5-sulfoisophthalic acid and 1,3-bis(4-pyridyl)propane, the latter serving as an auxiliary ligand. This method has proven to be a simpler approach compared to those described in the literature. The compounds were characterized by X-ray single crystal diffraction, FT-IR and Raman spectroscopy, and elemental analysis. Structural analysis revealed a significant correlation between atomic number of the lanthanide ion, unit cell parameters, and space group. On the other hand, the Hirshfeld surface analysis and the two-dimensional fingerprint plot revealed that the set of the intermolecular forces remains unchanged across different lanthanide ion.</div></div>","PeriodicalId":20278,"journal":{"name":"Polyhedron","volume":"264 ","pages":"Article 117243"},"PeriodicalIF":2.4000,"publicationDate":"2024-09-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polyhedron","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0277538724004194","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}

引用次数: 0

Abstract

This work presents the synthesis and structural characterization of eight isostructural 1D coordination polymers formed by the coordination of 5-sulfoisophthalic acid with various lanthanides ions: Ln =

C e (I I I), \Pr (I I I), S m (I I I), G d (I I I), D y (I I I),

H o (I I I), E r (I I I) a n d T m (I I I)

. The structures were synthetized via a two-step process, wherein a solution of lanthanide ions was added to a mixture of 5-sulfoisophthalic acid and 1,3-bis(4-pyridyl)propane, the latter serving as an auxiliary ligand. This method has proven to be a simpler approach compared to those described in the literature. The compounds were characterized by X-ray single crystal diffraction, FT-IR and Raman spectroscopy, and elemental analysis. Structural analysis revealed a significant correlation between atomic number of the lanthanide ion, unit cell parameters, and space group. On the other hand, the Hirshfeld surface analysis and the two-dimensional fingerprint plot revealed that the set of the intermolecular forces remains unchanged across different lanthanide ion.

Abstract Image

查看原文本刊更多论文

由 5-磺基间苯二甲酸和镧系离子形成的八种等结构配位聚合物的结构和合成研究

本研究介绍了 5-磺基间苯二甲酸与各种镧系离子配位形成的八种等结构一维配位聚合物的合成和结构特征：Ln = CeIII、PrIII、SmIII、GdIII、DyIII、HoIII、Er(III)和Tm(III)。这些结构是通过两步法合成的，即把镧系离子溶液加入 5-磺基间苯二甲酸和 1,3-双（4-吡啶基）丙烷的混合物中，后者作为辅助配体。事实证明，与文献中描述的方法相比，这种方法更为简单。这些化合物通过 X 射线单晶衍射、傅立叶变换红外光谱和拉曼光谱以及元素分析进行了表征。结构分析表明，镧系元素的原子序数、单胞参数和空间群之间存在显著的相关性。另一方面，Hirshfeld 表面分析和二维指纹图显示，不同镧系元素的分子间作用力保持不变。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Polyhedron 化学-晶体学

CiteScore

4.90

自引率

7.70%

发文量

515

审稿时长

2 months

期刊介绍： Polyhedron publishes original, fundamental, experimental and theoretical work of the highest quality in all the major areas of inorganic chemistry. This includes synthetic chemistry, coordination chemistry, organometallic chemistry, bioinorganic chemistry, and solid-state and materials chemistry. Papers should be significant pieces of work, and all new compounds must be appropriately characterized. The inclusion of single-crystal X-ray structural data is strongly encouraged, but papers reporting only the X-ray structure determination of a single compound will usually not be considered. Papers on solid-state or materials chemistry will be expected to have a significant molecular chemistry component (such as the synthesis and characterization of the molecular precursors and/or a systematic study of the use of different precursors or reaction conditions) or demonstrate a cutting-edge application (for example inorganic materials for energy applications). Papers dealing only with stability constants are not considered.