N-Heterocyclic Carbene Catalysis for Polycyclic Benzazepines Assembly: Regioselective Intramolecular Tandem Radical Cyclization.

IF 4.9 1区化学 Q1 CHEMISTRY, ORGANIC

Organic Letters Pub Date : 2024-10-25 Epub Date: 2024-10-11 DOI:10.1021/acs.orglett.4c03303

Zhiming Feng, Lili Wu, Cong-Ying Zhou, Chengming Wang

引用次数: 0

Abstract

A variety of polycyclic benzazepines were rapidly constructed by NHC-catalyzed regioselective redox-neutral intramolecular tandem cyclization. Initial mechanistic studies revealed that a SET radical process was possibly involved.

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N-Heterocyclic Carbene Catalysis for Polycyclic Benzazepines Assembly：区域选择性分子内串联自由基环化。

通过 NHC 催化的区域选择性氧化还原中性分子内串联环化反应，快速构建了多种多环苯并氮杂卓。初步的机理研究表明，其中可能涉及 SET 自由基过程。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Organic Letters 化学-有机化学

CiteScore

9.30

自引率

11.50%

发文量

1607

审稿时长

1.5 months

期刊介绍： Organic Letters invites original reports of fundamental research in all branches of the theory and practice of organic, physical organic, organometallic,medicinal, and bioorganic chemistry. Organic Letters provides rapid disclosure of the key elements of significant studies that are of interest to a large portion of the organic community. In selecting manuscripts for publication, the Editors place emphasis on the originality, quality and wide interest of the work. Authors should provide enough background information to place the new disclosure in context and to justify the rapid publication format. Back-to-back Letters will be considered. Full details should be reserved for an Article, which should appear in due course.