Superlattice Assembly for Empowering Metal Nanoclusters

IF 16.4 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Accounts of Chemical Research Pub Date : 2024-10-07 DOI:10.1021/acs.accounts.4c00521

Hao Li, Xi Kang, Manzhou Zhu

引用次数: 0

Abstract

Atomically precise metal nanoclusters, serving as an aggregation state of metal atoms, display unique physicochemical properties owing to their ultrasmall sizes with discrete electronic energy levels and strong quantum size effects. Such intriguing properties endow nanoclusters with potential utilization as efficient nanomaterials in catalysis, electron transfer, drug delivery, photothermal conversion, optical control, etc. With the assistance of atomically precise operations and theoretical calculations on metal nanoclusters, significant progress has been accomplished in illustrating their structure–performance correlations at the single-molecule level. Such research achievements, in turn, have contributed to the rational design and customization of functional nanoclusters and cluster-based nanomaterials.

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超晶格组装助力金属纳米簇

原子精密金属纳米团簇是金属原子的聚集态，由于其超小型尺寸、离散的电子能级和强大的量子尺寸效应，显示出独特的物理化学特性。这些奇妙的特性赋予了纳米团簇作为高效纳米材料在催化、电子传输、药物输送、光热转换、光学控制等领域的潜在用途。在对金属纳米团簇进行原子精确操作和理论计算的帮助下，在单分子水平上阐明其结构-性能相关性方面取得了重大进展。这些研究成果反过来又促进了功能纳米团簇和基于团簇的纳米材料的合理设计和定制。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Accounts of Chemical Research 化学-化学综合

CiteScore

31.40

自引率

1.10%

发文量

312

审稿时长

2 months

期刊介绍： Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.