Hiroyuki Y. Yasuda , Yusuke Yamada , Masato Onishi , Hiroki Suzuki , Ken Cho , Satoshi Ichikawa , Takeshi Nagase
{"title":"Stress increase by nanoscale hcp precipitates in HfNbTaTiZr high entropy alloys","authors":"Hiroyuki Y. Yasuda , Yusuke Yamada , Masato Onishi , Hiroki Suzuki , Ken Cho , Satoshi Ichikawa , Takeshi Nagase","doi":"10.1016/j.scriptamat.2024.116401","DOIUrl":null,"url":null,"abstract":"<div><div>HfNbTaTiZr high entropy alloys show a stress increase around 873 K, especially in the single crystals. At 873 K, the bcc single phase is decomposed into the bcc1 and bcc2 phases due to spinodal decomposition with composition modulation along 〈100〉 direction. The bcc1 phase has Zr- and Hf-rich composition, while Nb and Ta are enriched in the bcc2 phase. Next, the hcp phase is precipitated along the bcc1 phase. As a result, the hcp phase is aligned parallel to {100} plane of the bcc phase. The fine hcp phase acts as a strong barrier to the dislocation motion, resulting in the stress increase at 873 K.</div></div>","PeriodicalId":423,"journal":{"name":"Scripta Materialia","volume":"255 ","pages":"Article 116401"},"PeriodicalIF":5.3000,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Scripta Materialia","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1359646224004366","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
HfNbTaTiZr high entropy alloys show a stress increase around 873 K, especially in the single crystals. At 873 K, the bcc single phase is decomposed into the bcc1 and bcc2 phases due to spinodal decomposition with composition modulation along 〈100〉 direction. The bcc1 phase has Zr- and Hf-rich composition, while Nb and Ta are enriched in the bcc2 phase. Next, the hcp phase is precipitated along the bcc1 phase. As a result, the hcp phase is aligned parallel to {100} plane of the bcc phase. The fine hcp phase acts as a strong barrier to the dislocation motion, resulting in the stress increase at 873 K.
期刊介绍:
Scripta Materialia is a LETTERS journal of Acta Materialia, providing a forum for the rapid publication of short communications on the relationship between the structure and the properties of inorganic materials. The emphasis is on originality rather than incremental research. Short reports on the development of materials with novel or substantially improved properties are also welcomed. Emphasis is on either the functional or mechanical behavior of metals, ceramics and semiconductors at all length scales.