Metal ion-driven formation of 2H-silolides and -germolides.

IF 4.3 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2024-10-03 DOI:10.1039/d4cc03984j

Chenghuan Liu, Marc Schmidtmann, Thomas Müller

引用次数: 0

Abstract

The synthesis of potassio-1H-silolides and -germolides substituted with an amidinate-stabilized silylene is reported. Both anions undergo a thermal rearrangement to the 2H-isomer yielding cyclic sila- and germavinyl anions. The reaction is driven by complex formation with metal ions.

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金属离子驱动的 2H-硅烷化物和-锗化物的形成。

报告了用脒基稳定的硅烷基取代的钾硫代-1H-硅烷和-germolides 的合成。这两种阴离子都会发生热重排，生成 2H 异构体，从而产生环状硅烷基和锗烷基阴离子。该反应由与金属离子形成的络合物驱动。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.