Synthesis of new polycyclic adducts based on perhydrotetraazatetracene

IF 1.7 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Russian Chemical Bulletin Pub Date : 2024-09-19 DOI:10.1007/s11172-024-4353-0

E. B. Rakhimova, V. Yu. Kirsanov

引用次数: 0

Abstract

New N,N′-disubstituted perhydrohexaazadibenzo[fg,op]tetracenes with the (R*,R*,R*,R*) configuration of the chiral centers were synthesized by a one-pot catalytic heterocyclization of perhydrotetraazatetracene with formaldehyde and various primary amines as well as by the catalytic recyclization reaction of 1,3,5-trisubstituted 1,3,5-triazinanes with perhydrotetraazatetracene. The structures of all synthesized compounds were confirmed by NMR spectroscopy and high-resolution mass spectrometry.

查看原文本刊更多论文

基于全氢四氮杂蒽的新型多环加合物的合成

通过甲醛和多种伯胺以及全氢四氮杂四苯与甲醛的一步催化异环化反应，合成了手性中心构型为 (R*,R*,R*.) 的新的 N,N′-二取代全氢六氮杂二苯并[fg,op]四烯、通过全氢四氮杂四苯与甲醛和各种伯胺的单锅催化异环化反应，以及 1,3,5-三取代的 1,3,5-三嗪与全氢四氮杂四苯的催化再化学反应，合成了手性中心构型为 (R*,R*,R*) 的全氢六氮杂二苯并[fg,op]四蒽。所有合成化合物的结构都通过核磁共振光谱和高分辨率质谱法得到了证实。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Russian Chemical Bulletin 化学-化学综合

CiteScore

2.70

自引率

47.10%

发文量

257

审稿时长

3-8 weeks

期刊介绍： Publishing nearly 500 original articles a year, by leading Scientists from Russia and throughout the world, Russian Chemical Bulletin is a prominent international journal. The coverage of the journal spans practically all areas of fundamental chemical research and is presented in five sections: General and Inorganic Chemistry; Physical Chemistry; Organic Chemistry; Organometallic Chemistry; Chemistry of Natural Compounds and Bioorganic Chemistry.