Nicholas F. Scherschel, Matthias Zeller, Davin G. Piercey
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引用次数: 0
Abstract
Azoxy coupling of 5-amino-1-methyl-tetrazole, 5-amino-2-methyl-tetrazole, and 5-amino-1-methoxy-tetrazole was performed by reacting each with various oxidants. These reactions revealed aqueous Oxone to be the most facile system for yielding the azoxy couple for the previously mentioned tetrazoles. Chemical and structural characterization of each novel azoxy-coupled tetrazole was conducted with 1H NMR, 13C NMR, HRMS, and single-crystal x-ray diffraction. Energetic characterization was evaluated by analysis of each compounds' single crystal x-ray diffraction density, impact sensitivity, friction sensitivity, and decomposition temperature. All compounds were found to be very sensitive to impact and friction stimuli.
期刊介绍：
The Journal of Heterocyclic Chemistry is interested in publishing research on all aspects of heterocyclic chemistry, especially development and application of efficient synthetic methodologies and strategies for the synthesis of various heterocyclic compounds. In addition, Journal of Heterocyclic Chemistry promotes research in other areas that contribute to heterocyclic synthesis/application, such as synthesis design, reaction techniques, flow chemistry and continuous processing, multiphase catalysis, green chemistry, catalyst immobilization and recycling.
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