Optimizing the conversion of waste plastic into suitable engine fuel through response surface methodology

IF 6.9 2区 环境科学与生态学 Q1 ENGINEERING, CHEMICAL
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Abstract

The extensive utilization of plastic in daily life has significantly contributed to per-day waste generation. The conversion of waste plastic through pyrolysis into fossil fuel is a promising solution to waste management and energy crises. The precise control of the process parameters in the pyrolysis would be a sustainable business model. Since the optimization of process parameters for production yield and the physicochemical properties of waste plastic oil have been underexplored. So, the current research optimized input process parameters of pyrolysis through response surface methodology using a central composite design. The input parameters of the experimental design were reaction temperature (350°C-550°C), retention time (60–300 min), nitrogen flow rate (0–40 ml/s), and ZSM-5 catalyst concentration (1–5 wt%). Waste plastic is converted into the optimized yield of oil (85 %), solid (3 %), and syngas (12 %). Waste plastic oil (WPO) had optimal results of physicochemical properties like heating value (48 MJ/kg), flash point (60 °C), kinematic viscosity (2.1 mm2/s), and density (820 kg/m3). American Society for Testing and Materials Standards validated the produced WPO, which had better fuel properties than petroleum diesel. However, the application of other sustainable biocatalysts and uncondensed gas may be explored in future research.

通过响应面方法优化将废塑料转化为合适的发动机燃料
日常生活中塑料的广泛使用极大地增加了每天的废物产生量。通过热解将废塑料转化为化石燃料,是解决废物管理和能源危机的一个可行方案。精确控制热解过程中的工艺参数将是一种可持续的商业模式。由于对废塑料油的产量和理化性质的工艺参数优化探索不足。因此,本研究采用中心复合设计,通过响应面方法优化热解的输入工艺参数。实验设计的输入参数为反应温度(350°C-550°C)、停留时间(60-300 分钟)、氮气流速(0-40 毫升/秒)和 ZSM-5 催化剂浓度(1-5 wt%)。废塑料被转化为油(85%)、固体(3%)和合成气(12%)的最佳产量。废塑料油(WPO)具有最佳的物理化学特性,如热值(48 MJ/kg)、闪点(60 °C)、运动粘度(2.1 mm2/s)和密度(820 kg/m3)。美国测试与材料协会标准验证了所生产的 WPO 比石油柴油具有更好的燃料特性。不过,在未来的研究中,还可以探索其他可持续生物催化剂和未凝结气体的应用。
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来源期刊
Process Safety and Environmental Protection
Process Safety and Environmental Protection 环境科学-工程:化工
CiteScore
11.40
自引率
15.40%
发文量
929
审稿时长
8.0 months
期刊介绍: The Process Safety and Environmental Protection (PSEP) journal is a leading international publication that focuses on the publication of high-quality, original research papers in the field of engineering, specifically those related to the safety of industrial processes and environmental protection. The journal encourages submissions that present new developments in safety and environmental aspects, particularly those that show how research findings can be applied in process engineering design and practice. PSEP is particularly interested in research that brings fresh perspectives to established engineering principles, identifies unsolved problems, or suggests directions for future research. The journal also values contributions that push the boundaries of traditional engineering and welcomes multidisciplinary papers. PSEP's articles are abstracted and indexed by a range of databases and services, which helps to ensure that the journal's research is accessible and recognized in the academic and professional communities. These databases include ANTE, Chemical Abstracts, Chemical Hazards in Industry, Current Contents, Elsevier Engineering Information database, Pascal Francis, Web of Science, Scopus, Engineering Information Database EnCompass LIT (Elsevier), and INSPEC. This wide coverage facilitates the dissemination of the journal's content to a global audience interested in process safety and environmental engineering.
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