{"title":"Construction of Nitrogen-Rich Energetic Isomers Containing Multiple Hydrogen Bond Networks","authors":"Hanghong Fan, Jie Tang, Caijin Lei, Wei Hu, Hongwei Yang, Chuan Xiao, Guangbin Cheng","doi":"10.1021/acs.orglett.4c02867","DOIUrl":null,"url":null,"abstract":"Nitrogen-rich energetic materials have been the focus of a few studies on their isomers. Novel nitrogen-rich energetic compounds <b>TZ</b>, <b>DTZ</b>, and <b>NTZ</b> were synthesized through simple steps. The hydrogen bond networks significantly enhanced their properties (<b>TZ</b>, <i>T</i><sub>d</sub> = 290 °C and <i>D</i><sub>v</sub> = 8370 m s<sup>–1</sup>; <b>DTZ</b>, <i>T</i><sub>d</sub> = 282 °C and <i>D</i><sub>v</sub> = 8392 m s<sup>–1</sup>; and <b>NTZ</b>, <i>T</i><sub>d</sub> = 272 °C and <i>D</i><sub>v</sub> = 8762 m s<sup>–1</sup>), which are superior to their isomers. This realized a balance between the energy and stability of polycyclic tetrazoles, providing insights for high-performance energetic materials.","PeriodicalId":54,"journal":{"name":"Organic Letters","volume":null,"pages":null},"PeriodicalIF":4.9000,"publicationDate":"2024-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Organic Letters","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1021/acs.orglett.4c02867","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
引用次数: 0
Abstract
Nitrogen-rich energetic materials have been the focus of a few studies on their isomers. Novel nitrogen-rich energetic compounds TZ, DTZ, and NTZ were synthesized through simple steps. The hydrogen bond networks significantly enhanced their properties (TZ, Td = 290 °C and Dv = 8370 m s–1; DTZ, Td = 282 °C and Dv = 8392 m s–1; and NTZ, Td = 272 °C and Dv = 8762 m s–1), which are superior to their isomers. This realized a balance between the energy and stability of polycyclic tetrazoles, providing insights for high-performance energetic materials.
期刊介绍:
Organic Letters invites original reports of fundamental research in all branches of the theory and practice of organic, physical organic, organometallic,medicinal, and bioorganic chemistry. Organic Letters provides rapid disclosure of the key elements of significant studies that are of interest to a large portion of the organic community. In selecting manuscripts for publication, the Editors place emphasis on the originality, quality and wide interest of the work. Authors should provide enough background information to place the new disclosure in context and to justify the rapid publication format. Back-to-back Letters will be considered. Full details should be reserved for an Article, which should appear in due course.