Mechanically tunable fluorescence emission and patterned image of a conjugated polymer with an intramolecular stacking structure in an elastomeric silicone rubber matrix

IF 3.1 3区 化学 Q2 POLYMER SCIENCE
Dong Cheul Han, Heesang Kim, Chang-Lyoul Lee, Giseop Kwak
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引用次数: 0

Abstract

A hybrid film that exhibits reversible fluorescence (FL) is prepared by embedding a conjugated polymer, having an intramolecular stacking structure of the side phenyl rings, in a highly dispersed state into a silicone elastomer. The hybrid film experiences significant FL quenching during stretching and restores its original FL when the external stress is removed. In particular, the hybrid film manufactured using a shadow-masked, plasma-treated silicone elastomer provides a high-resolution FL image, which disappears when the film is stretched and reappears when the external stress is removed. The hybrid film can be applied as a strain-gauge sensor or a security film with embedded images that can be mechanically erased and regenerated.

Graphical abstract

Abstract Image

在弹性硅橡胶基体中具有分子内堆积结构的共轭聚合物的机械可调荧光发射和图案图像
通过将具有分子内侧苯基环堆叠结构的共轭聚合物以高度分散的状态嵌入硅树脂弹性体中,制备出了一种具有可逆荧光(FL)的混合薄膜。混合薄膜在拉伸过程中会出现明显的 FL 淬火现象,当外部应力消除后,又会恢复原来的 FL。特别是,使用阴影掩蔽、等离子处理的硅树脂弹性体制造的混合薄膜可提供高分辨率的 FL 图像,该图像在薄膜拉伸时消失,而在去除外应力后又重新出现。这种混合薄膜可用作应变计传感器或带有可机械擦除和再生的嵌入式图像的安全薄膜。
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来源期刊
Polymer Bulletin
Polymer Bulletin 化学-高分子科学
CiteScore
6.00
自引率
6.20%
发文量
0
审稿时长
5.5 months
期刊介绍: "Polymer Bulletin" is a comprehensive academic journal on polymer science founded in 1988. It was founded under the initiative of the late Mr. Wang Baoren, a famous Chinese chemist and educator. This journal is co-sponsored by the Chinese Chemical Society, the Institute of Chemistry, and the Chinese Academy of Sciences and is supervised by the China Association for Science and Technology. It is a core journal and is publicly distributed at home and abroad. "Polymer Bulletin" is a monthly magazine with multiple columns, including a project application guide, outlook, review, research papers, highlight reviews, polymer education and teaching, information sharing, interviews, polymer science popularization, etc. The journal is included in the CSCD Chinese Science Citation Database. It serves as the source journal for Chinese scientific and technological paper statistics and the source journal of Peking University's "Overview of Chinese Core Journals."
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