CuX-Based MOFs as functional materials for adsorption, catalytic, and sensing applications

IF 5.7 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY
Léo Boivin and Pierre D. Harvey
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引用次数: 0

Abstract

Metal–organic frameworks (MOFs) built with nodes of copper(I) halides as metallic nodes have experienced a recent increase in interest as these porous materials exhibit rich physical, photophysical, and chemical properties and applications. In this comprehensive review, these properties and applications are surveyed and described, and include highly luminescent materials exhibiting long-lived excited state lifetimes, high triplet populations, large Stokes shift, etc., which are also of high porosity and rigidity. The auspicious combination of these properties lends them interesting applications such as selective gas adsorption and separation, capture of pollutants, catalysis, and sensing, among others.

Abstract Image

Abstract Image

基于 CuX 的 MOFs 作为吸附、催化和传感应用的功能材料
以铜(I)卤化物为金属节点构建的金属有机框架(MOFs)近年来受到越来越多的关注,因为这些多孔材料具有丰富的物理、光物理和化学特性及应用。本综述对这些特性和应用进行了调查和描述,其中包括具有长寿命激发态寿命、高三重态种群、大斯托克斯位移等特性的高发光材料,它们还具有高孔隙率和高刚性。这些特性的完美结合使它们在选择性气体吸附和分离、污染物捕获、催化和传感等方面得到了有趣的应用。
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来源期刊
Journal of Materials Chemistry C
Journal of Materials Chemistry C MATERIALS SCIENCE, MULTIDISCIPLINARY-PHYSICS, APPLIED
CiteScore
10.80
自引率
6.20%
发文量
1468
期刊介绍: The Journal of Materials Chemistry is divided into three distinct sections, A, B, and C, each catering to specific applications of the materials under study: Journal of Materials Chemistry A focuses primarily on materials intended for applications in energy and sustainability. Journal of Materials Chemistry B specializes in materials designed for applications in biology and medicine. Journal of Materials Chemistry C is dedicated to materials suitable for applications in optical, magnetic, and electronic devices. Example topic areas within the scope of Journal of Materials Chemistry C are listed below. This list is neither exhaustive nor exclusive. Bioelectronics Conductors Detectors Dielectrics Displays Ferroelectrics Lasers LEDs Lighting Liquid crystals Memory Metamaterials Multiferroics Photonics Photovoltaics Semiconductors Sensors Single molecule conductors Spintronics Superconductors Thermoelectrics Topological insulators Transistors
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