{"title":"CuX-Based MOFs as functional materials for adsorption, catalytic, and sensing applications","authors":"Léo Boivin and Pierre D. Harvey","doi":"10.1039/D4TC03093A","DOIUrl":null,"url":null,"abstract":"<p >Metal–organic frameworks (MOFs) built with nodes of copper(<small>I</small>) halides as metallic nodes have experienced a recent increase in interest as these porous materials exhibit rich physical, photophysical, and chemical properties and applications. In this comprehensive review, these properties and applications are surveyed and described, and include highly luminescent materials exhibiting long-lived excited state lifetimes, high triplet populations, large Stokes shift, <em>etc.</em>, which are also of high porosity and rigidity. The auspicious combination of these properties lends them interesting applications such as selective gas adsorption and separation, capture of pollutants, catalysis, and sensing, among others.</p>","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":null,"pages":null},"PeriodicalIF":8.3000,"publicationDate":"2024-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Applied Materials & Interfaces","FirstCategoryId":"1","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2024/tc/d4tc03093a","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Metal–organic frameworks (MOFs) built with nodes of copper(I) halides as metallic nodes have experienced a recent increase in interest as these porous materials exhibit rich physical, photophysical, and chemical properties and applications. In this comprehensive review, these properties and applications are surveyed and described, and include highly luminescent materials exhibiting long-lived excited state lifetimes, high triplet populations, large Stokes shift, etc., which are also of high porosity and rigidity. The auspicious combination of these properties lends them interesting applications such as selective gas adsorption and separation, capture of pollutants, catalysis, and sensing, among others.
期刊介绍：
ACS Applied Materials & Interfaces is a leading interdisciplinary journal that brings together chemists, engineers, physicists, and biologists to explore the development and utilization of newly-discovered materials and interfacial processes for specific applications. Our journal has experienced remarkable growth since its establishment in 2009, both in terms of the number of articles published and the impact of the research showcased. We are proud to foster a truly global community, with the majority of published articles originating from outside the United States, reflecting the rapid growth of applied research worldwide.
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