Mesoporous Activated Carbon from Sunflower (Helianthus annuus) Seed Pericarp for Crystal Violet Dye Removal: Numerical Desirability Optimization and Mechanism Study
Ali H. Jawad, Nursuhada Salleh, Zeid A. ALOthman, Rangabhashiyam Selvasembian
{"title":"Mesoporous Activated Carbon from Sunflower (Helianthus annuus) Seed Pericarp for Crystal Violet Dye Removal: Numerical Desirability Optimization and Mechanism Study","authors":"Ali H. Jawad, Nursuhada Salleh, Zeid A. ALOthman, Rangabhashiyam Selvasembian","doi":"10.1007/s11270-024-07477-8","DOIUrl":null,"url":null,"abstract":"<p>In this work, sunflower (<i>Helianthus annuus</i>) seed pericarp (SSPC) was converted into mesoporous activated carbon (SSPCAC) <i>via</i> microwave-assisted ZnCl<sub>2</sub> activation to be a cost-effective and renewable adsorbent for crystal violet (CV) dye removal. The obtained SSPCAC exhibits a preferable surface area of 641 m<sup>2</sup>/g with mesoporous characteristics. A statistical optimization by Box-Behnken Design (BBD) with Response Surface Methodology (RSM) was adopted to achieve the optimal operational conditions for CV dye including SSPCAC dose, solution pH, and contact time. Moreover, desirability functions confirm the maximum CV removal of 91% was attended at SSPC-AC dose (0.083 g/100 mL), solution pH (9.8), and contact time (5.38 min). Thus, the equilibrium data were best described by the Langmuir isotherm model with a maximum adsorption capacity of 111.9 mg/g at 25 <sup>0</sup>C. Thus, the adsorption kinetics were well described by a pseudo-second order (PSO) model. The adsorption mechanism of CV onto SSPCAC surface can be assigned to the electrostatic attraction, hydrogen bonding, pore filling, and pi-pi interactions. This research highlights the potential of sunflower seed pericarp as a renewable precursor for activated carbon production with promising applications in toxic dye removal from wastewater.</p>","PeriodicalId":808,"journal":{"name":"Water, Air, & Soil Pollution","volume":null,"pages":null},"PeriodicalIF":3.8000,"publicationDate":"2024-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Water, Air, & Soil Pollution","FirstCategoryId":"6","ListUrlMain":"https://doi.org/10.1007/s11270-024-07477-8","RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENVIRONMENTAL SCIENCES","Score":null,"Total":0}
引用次数: 0
Abstract
In this work, sunflower (Helianthus annuus) seed pericarp (SSPC) was converted into mesoporous activated carbon (SSPCAC) via microwave-assisted ZnCl2 activation to be a cost-effective and renewable adsorbent for crystal violet (CV) dye removal. The obtained SSPCAC exhibits a preferable surface area of 641 m2/g with mesoporous characteristics. A statistical optimization by Box-Behnken Design (BBD) with Response Surface Methodology (RSM) was adopted to achieve the optimal operational conditions for CV dye including SSPCAC dose, solution pH, and contact time. Moreover, desirability functions confirm the maximum CV removal of 91% was attended at SSPC-AC dose (0.083 g/100 mL), solution pH (9.8), and contact time (5.38 min). Thus, the equilibrium data were best described by the Langmuir isotherm model with a maximum adsorption capacity of 111.9 mg/g at 25 0C. Thus, the adsorption kinetics were well described by a pseudo-second order (PSO) model. The adsorption mechanism of CV onto SSPCAC surface can be assigned to the electrostatic attraction, hydrogen bonding, pore filling, and pi-pi interactions. This research highlights the potential of sunflower seed pericarp as a renewable precursor for activated carbon production with promising applications in toxic dye removal from wastewater.
期刊介绍:
Water, Air, & Soil Pollution is an international, interdisciplinary journal on all aspects of pollution and solutions to pollution in the biosphere. This includes chemical, physical and biological processes affecting flora, fauna, water, air and soil in relation to environmental pollution. Because of its scope, the subject areas are diverse and include all aspects of pollution sources, transport, deposition, accumulation, acid precipitation, atmospheric pollution, metals, aquatic pollution including marine pollution and ground water, waste water, pesticides, soil pollution, sewage, sediment pollution, forestry pollution, effects of pollutants on humans, vegetation, fish, aquatic species, micro-organisms, and animals, environmental and molecular toxicology applied to pollution research, biosensors, global and climate change, ecological implications of pollution and pollution models. Water, Air, & Soil Pollution also publishes manuscripts on novel methods used in the study of environmental pollutants, environmental toxicology, environmental biology, novel environmental engineering related to pollution, biodiversity as influenced by pollution, novel environmental biotechnology as applied to pollution (e.g. bioremediation), environmental modelling and biorestoration of polluted environments.
Articles should not be submitted that are of local interest only and do not advance international knowledge in environmental pollution and solutions to pollution. Articles that simply replicate known knowledge or techniques while researching a local pollution problem will normally be rejected without review. Submitted articles must have up-to-date references, employ the correct experimental replication and statistical analysis, where needed and contain a significant contribution to new knowledge. The publishing and editorial team sincerely appreciate your cooperation.
Water, Air, & Soil Pollution publishes research papers; review articles; mini-reviews; and book reviews.