Preparation of Metal-Supported Nanostructured Zeolite Catalysts and their Applications in the Upgrading of Biomass-Derived Furans: Advances and Prospects

IF 3 4区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

ChemPlusChem Pub Date : 2024-09-04 DOI:10.1002/cplu.202400343

Peerapol Pornsetmetakul, Narasiri Maineawklang, Chularat Wattanakit

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Abstract

The development of platform chemicals derived from biomass, in particular, 5-hydroxymethylfurfural (5-HMF) and furfural (FUR), is of crucial importance in biorefinery. Over the past decades, metal-supported nanostructured zeolites, in particular, metal-supported hierarchically porous zeolites or metal-encapsulated zeolites, have been extensively elaborated because of their multiple functionalities and superior properties, for example, shape-selectivity, (hydro)thermal stability, tunable acidity and basicity, redox properties, improved diffusion, and intimacy of multiple active sites. In this review, the effects of such properties of metal-supported nanostructured zeolites on the enhanced catalytic performances in furanic compound upgrading are discussed. In addition, the recent rational design of metal-supported nanostructured zeolites is exemplified. Consequently, the ongoing challenges for further developing metal-supported nanostructured zeolites-based catalysts and their applications in HMF and FUR upgrading are identified.

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金属支撑纳米结构沸石催化剂的制备及其在生物质衍生呋喃升级中的应用：进展与前景》。

开发从生物质中提取的平台化学品，特别是 5-hydroxymethylfurfural (5-HMF) 和糠醛 (FUR)，在生物精炼中至关重要。在过去的几十年中，金属支撑的纳米结构沸石，特别是金属支撑的分层多孔沸石或金属封装沸石，因其具有多种功能和优越性能，如形状选择性、（水）热稳定性、可调酸碱性、氧化还原性、更好的扩散性和多个活性位点的亲和性，而得到了广泛的研究。本综述讨论了金属支撑纳米结构沸石的这些特性对提高呋喃化合物升级催化性能的影响。此外，还举例说明了近期金属支撑纳米结构沸石的合理设计。因此，确定了进一步开发基于金属支撑纳米结构沸石的催化剂及其在 HMF 和 FUR 升级中的应用所面临的挑战。

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来源期刊

ChemPlusChem CHEMISTRY, MULTIDISCIPLINARY-

CiteScore

5.90

自引率

0.00%

发文量

200

审稿时长

1 months

期刊介绍： ChemPlusChem is a peer-reviewed, general chemistry journal that brings readers the very best in multidisciplinary research centering on chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. Fully comprehensive in its scope, ChemPlusChem publishes articles covering new results from at least two different aspects (subfields) of chemistry or one of chemistry and one of another scientific discipline (one chemistry topic plus another one, hence the title ChemPlusChem). All suitable submissions undergo balanced peer review by experts in the field to ensure the highest quality, originality, relevance, significance, and validity.