Fully biobased approach for sustainable flame retardancy, antibacterial and anti-UV modification of silk fabric

Abstract

The versatile modification of silk fabric using a fully biobased approach is intriguing. In this study, phytic acid and vanillin, which are plant extracts, were utilized to synthesize reactive vanillin phytate ester for modifying silk fabric to achieve durable flame retardancy, antibacterial and anti-UV performance. The multifunctional properties, thermal resistance, smoke and heat suppression capacity, flame-retardant durability and mechanism of modified silk fabrics were investigated. The vanillin phytate ester imparted high antimicrobial and UV resistance to silk fabric, achieving a 97 % inhibition rate against Escherichia coli and reaching an “excellent” level of UV protection. The modified silk fabric also possessed the self-extinguishing capacity, with a limiting oxygen index value as high as 33.5 %. There was also a significant reduction of 71.7 % in peak heat release and 40 % in smoke release compared with those of the original silk. After undergoing 20 washing cycles, the modified silk fabrics also self-extinguished and passed the vertical burning test, and such good washing resistance was achieved by the Schiff base cross-linking of vanillin phytate ester on the silk fabric. An intumescent flame-retardant mechanism was also identified by char residue analyses, which was driven by the synergistic charring action of phosphate groups and aromatic structures.