MIL-125 and its derivatives based photoelectrodes for photoelectrochemical applications

IF 9.1 2区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Progress in Solid State Chemistry Pub Date : 2024-08-27 DOI:10.1016/j.progsolidstchem.2024.100476

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引用次数: 0

Abstract

Among the Material of Institute Lavoisier (MIL) compounds, MIL-125 has been proved to be potentially high photoactive electrode in the photoelectrochemical (PEC) devices. The great progress has been achieved in the preparation, structural optimization and applications of MIL-125, especially in the PEC technology, as witnessed by the quick increase in the number of published papers. Consequently, a comprehensive review of the current research status of MIL-125 based electrodes in PEC is warranted. This review provides an in-depth analysis of various PEC applications employing MIL-125 based photoelectrodes, such as sensing (including PEC biosensors, organic pollutant detection, and heavy metal ion sensing), water splitting for hydrogen production, photovoltaic cells (including dye-sensitized solar cells, quantum dot-sensitized solar cells, perovskite solar cells, and organic solar cells), photoelectrocatalysis, and photocathodic protection. Particular emphasis is placed on the signal amplification strategies, modification design, and reaction mechanisms of MIL-125 for PEC applications. Finally, the development opportunities and unsolved challenges associated with MIL-125 based materials in the PEC field are also highlighted. This comprehensive review is expected to expand the knowledge of recent advancements in MIL-125 and its derivatives modified electrodes and encourage researchers to promote the construction of efficient PEC systems.

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基于 MIL-125 及其衍生物的光电电极在光电化学中的应用

在拉瓦锡研究所材料（MIL）化合物中，MIL-125 已被证明是光电化学（PEC）设备中潜在的高光活性电极。MIL-125 在制备、结构优化和应用方面取得了巨大进步，尤其是在光致化学电池技术方面，这一点从发表论文数量的快速增长中可见一斑。因此，有必要对基于 MIL-125 的 PEC 电极的研究现状进行全面回顾。本综述深入分析了采用 MIL-125 基光电电极的各种 PEC 应用，如传感（包括 PEC 生物传感器、有机污染物检测和重金属离子传感）、用于制氢的水分离、光伏电池（包括染料敏化太阳能电池、量子点敏化太阳能电池、过氧化物太阳能电池和有机太阳能电池）、光电催化和光阴极保护。特别强调了 MIL-125 在 PEC 应用中的信号放大策略、改性设计和反应机制。最后，还强调了基于 MIL-125 的材料在 PEC 领域的发展机遇和尚未解决的挑战。这篇全面的综述有望扩展人们对 MIL-125 及其衍生物改性电极最新进展的了解，并鼓励研究人员推动高效 PEC 系统的构建。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Progress in Solid State Chemistry 化学-无机化学与核化学

CiteScore

14.10

自引率

3.30%

发文量

期刊介绍： Progress in Solid State Chemistry offers critical reviews and specialized articles written by leading experts in the field, providing a comprehensive view of solid-state chemistry. It addresses the challenge of dispersed literature by offering up-to-date assessments of research progress and recent developments. Emphasis is placed on the relationship between physical properties and structural chemistry, particularly imperfections like vacancies and dislocations. The reviews published in Progress in Solid State Chemistry emphasize critical evaluation of the field, along with indications of current problems and future directions. Papers are not intended to be bibliographic in nature but rather to inform a broad range of readers in an inherently multidisciplinary field by providing expert treatises oriented both towards specialists in different areas of the solid state and towards nonspecialists. The authorship is international, and the subject matter will be of interest to chemists, materials scientists, physicists, metallurgists, crystallographers, ceramists, and engineers interested in the solid state.

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