{"title":"Synthesis, morphology and Raman spectroscopy of ZnS/Ag2S heteronanostructures","authors":"S.I. Sadovnikov, I.I. Leonidov, A.I. Gusev","doi":"10.1016/j.solidstatesciences.2024.107662","DOIUrl":null,"url":null,"abstract":"<div><p>Sulfide (ZnS)(Ag<sub>2</sub>S)<sub><em>x</em></sub> heteronanostructures of various composition were obtained by co-deposition from water colloidal solutions of silver and zinc nitrates using sodium sulfide as a sulfidizer and sodium citrate as a stabilizer. The formation of (ZnS)(Ag<sub>2</sub>S)<sub><em>x</em></sub> heteronanostructures was confirmed using the XRD, HAADF-STEM, SEM, EDX and Raman spectroscopy. The size of ZnS and Ag<sub>2</sub>S nanoparticles in heteronanostructures (ZnS)(Ag<sub>2</sub>S)<sub><em>x</em></sub> with <em>x</em> ≤ 0.01 is 2–4 and no more than 3 nm, respectively. Raman spectroscopy showed that addition of silver sulfide nanoparticles into (ZnS)(Ag<sub>2</sub>S)<sub><em>x</em></sub> heteronanostructures leads to Ag<sub>2</sub>S deposition onto the surface of ZnS nanoparticles. Doping ZnS with only 1 mol.% of colloidal Ag<sub>2</sub>S nanoparticles is sufficient to produce a silver sulfide shell on the surface of ZnS nanoparticles.</p></div>","PeriodicalId":432,"journal":{"name":"Solid State Sciences","volume":"156 ","pages":"Article 107662"},"PeriodicalIF":3.4000,"publicationDate":"2024-08-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Solid State Sciences","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1293255824002279","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
Sulfide (ZnS)(Ag2S)x heteronanostructures of various composition were obtained by co-deposition from water colloidal solutions of silver and zinc nitrates using sodium sulfide as a sulfidizer and sodium citrate as a stabilizer. The formation of (ZnS)(Ag2S)x heteronanostructures was confirmed using the XRD, HAADF-STEM, SEM, EDX and Raman spectroscopy. The size of ZnS and Ag2S nanoparticles in heteronanostructures (ZnS)(Ag2S)x with x ≤ 0.01 is 2–4 and no more than 3 nm, respectively. Raman spectroscopy showed that addition of silver sulfide nanoparticles into (ZnS)(Ag2S)x heteronanostructures leads to Ag2S deposition onto the surface of ZnS nanoparticles. Doping ZnS with only 1 mol.% of colloidal Ag2S nanoparticles is sufficient to produce a silver sulfide shell on the surface of ZnS nanoparticles.
期刊介绍：
Solid State Sciences is the journal for researchers from the broad solid state chemistry and physics community. It publishes key articles on all aspects of solid state synthesis, structure-property relationships, theory and functionalities, in relation with experiments.
Key topics for stand-alone papers and special issues:
-Novel ways of synthesis, inorganic functional materials, including porous and glassy materials, hybrid organic-inorganic compounds and nanomaterials
-Physical properties, emphasizing but not limited to the electrical, magnetical and optical features
-Materials related to information technology and energy and environmental sciences.
The journal publishes feature articles from experts in the field upon invitation.
Solid State Sciences - your gateway to energy-related materials.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
