Reactivity of the [HFe(CO)4]− hydride for the synthesis of low coordinated phosphorus derivatives

IF 2.7 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Inorganica Chimica Acta Pub Date : 2024-08-27 DOI:10.1016/j.ica.2024.122336

Anne-Marie Caminade

引用次数: 0

Abstract

The reaction of [X][Hfe(CO)₄] (X = mainly PPh₄, but also NEt₄, K and Ph₃PNPPh₃) with chlorophosphines for the synthesis of low coordinated phosphorus complexes is reviewed. Diphosphene (PP), phospha-alkene (PC<), phospha-allene (PCC<), and phosphide (>P) iron complexes have been in particular obtained, and characterized by ³¹P NMR, and by X-ray diffraction in several cases.

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[HFe(CO)4]-氢化物在合成低配位磷衍生物中的反应活性

本文综述了[X][Hfe(CO)4]（X = 主要是 PPh4，也包括 NEt4、K 和 Ph3PNPPh3）与氯膦反应合成低配位磷络合物的过程。特别是获得了二磷化烯 (PP)、磷化烯 (PC<)、磷化烯 (PCC<) 和磷化物 (>P) 铁络合物，并通过 31P NMR 和 X 射线衍射对其进行了表征。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Inorganica Chimica Acta 化学-无机化学与核化学

CiteScore

6.00

自引率

3.60%

发文量

440

审稿时长

35 days

期刊介绍： Inorganica Chimica Acta is an established international forum for all aspects of advanced Inorganic Chemistry. Original papers of high scientific level and interest are published in the form of Articles and Reviews. Topics covered include: • chemistry of the main group elements and the d- and f-block metals, including the synthesis, characterization and reactivity of coordination, organometallic, biomimetic, supramolecular coordination compounds, including associated computational studies; • synthesis, physico-chemical properties, applications of molecule-based nano-scaled clusters and nanomaterials designed using the principles of coordination chemistry, as well as coordination polymers (CPs), metal-organic frameworks (MOFs), metal-organic polyhedra (MPOs); • reaction mechanisms and physico-chemical investigations computational studies of metalloenzymes and their models; • applications of inorganic compounds, metallodrugs and molecule-based materials. Papers composed primarily of structural reports will typically not be considered for publication.