High-pressure phase equilibrium for carbon dioxide solubility with biofuels: Experimental and thermodynamic insights in 2,5-dimethylfuran and methyl levulinate

IF 3.4 3区 工程技术 Q2 CHEMISTRY, PHYSICAL
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引用次数: 0

Abstract

The solubility of carbon dioxide in two solvents, 2,5-dimethylfuran and methyl levulinate, were measured to high pressure, up to 9.1 MPa, at three different temperatures (283.15, 303.15 and 323.15) K. The new data were measured using both the isothermal synthetic technique and the variable volume synthetic method. Two methods were utilised to provide a level of data validation. The uncertainties in the measured data were critically estimated. The experimental phase equilibrium data were modeled using the Peng-Robinson equation of state and the Wong-Sandler mixing rule with a single set of binary interaction parameters for each system. The data indicated that the solubility of carbon dioxide in both 2,5-dimethylfuran and methyl levulinate at high pressures was relatively low, suggesting a low capacity of these biofuels to dissolve carbon dioxide at high pressure.

生物燃料中二氧化碳溶解度的高压相平衡:2,5-二甲基呋喃和乙酰丙酸甲酯的实验和热力学见解
在三种不同温度(283.15、303.15 和 323.15)K 下测量了二氧化碳在 2,5-二甲基呋喃和乙酰丙酸甲酯两种溶剂中的高压溶解度,最高可达 9.1 兆帕。使用这两种方法提供了一定程度的数据验证。对测量数据的不确定性进行了严格估算。使用彭-罗宾逊状态方程和黄-桑德勒混合规则对实验相平衡数据进行建模,每个系统使用一组二元相互作用参数。数据表明,在高压下二氧化碳在 2,5-二甲基呋喃和乙酰丙酸甲酯中的溶解度相对较低,这表明这些生物燃料在高压下溶解二氧化碳的能力较低。
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来源期刊
Journal of Supercritical Fluids
Journal of Supercritical Fluids 工程技术-工程:化工
CiteScore
7.60
自引率
10.30%
发文量
236
审稿时长
56 days
期刊介绍: The Journal of Supercritical Fluids is an international journal devoted to the fundamental and applied aspects of supercritical fluids and processes. Its aim is to provide a focused platform for academic and industrial researchers to report their findings and to have ready access to the advances in this rapidly growing field. Its coverage is multidisciplinary and includes both basic and applied topics. Thermodynamics and phase equilibria, reaction kinetics and rate processes, thermal and transport properties, and all topics related to processing such as separations (extraction, fractionation, purification, chromatography) nucleation and impregnation are within the scope. Accounts of specific engineering applications such as those encountered in food, fuel, natural products, minerals, pharmaceuticals and polymer industries are included. Topics related to high pressure equipment design, analytical techniques, sensors, and process control methodologies are also within the scope of the journal.
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