Some remarks on "Efficient removal of total arsenic (As3+/5+) from contaminated water by novel strategies mediated iron and plant extract activated waste flowers of marigold".

Chemosphere Pub Date : 2024-09-01 Epub Date: 2024-08-16 DOI:10.1016/j.chemosphere.2024.143063
Hai Nguyen Tran, Stéphane Simon, Jean-Claude Bollinger
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Abstract

We explain here that the authors of the article cited in the title have misrepresented the species of As(III) and As(V) in solutions and, in particular, have neglected their speciation as a function of pH. Their discussion of (ad)sorption mechanisms is therefore unsatisfactory, especially since organic matter (flower waste) and the presence of iron oxyhydroxides should be taken into account. Furthermore, the modeling of (ad)sorption kinetics and isotherms was based on linearized equations, whereas the corresponding nonlinear equations should have been used. Therefore, we believe that the authors of the original article should make corrections and additions to it. This Letter to the Editor is motivated by a concern to avoid the dissemination of approximate or even incorrect concepts in the scientific literature, which could mislead novice researchers.

关于 "以新型策略为介导的铁和植物提取物活化万寿菊废花高效去除污染水中的总砷(As3+/5+)"的一些评论。
我们在此说明,标题中引用的文章的作者错误地描述了溶液中 As(III) 和 As(V) 的种类,尤其是忽略了它们作为 pH 值函数的种类。因此,他们对(吸附)机制的讨论并不令人满意,特别是应该考虑到有机物(花卉废料)和铁氧氢氧化物的存在。此外,(吸附)动力学和等温线的建模是基于线性化方程,而相应的非线性方程本应使用。因此,我们认为原文作者应该对文章进行更正和补充。之所以写这封致编辑的信,是因为我们希望避免在科学文献中传播近似甚至不正确的概念,以免误导研究新手。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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