Synthesis of 3-(2,3,5,6-tetrafluoropyridinylthio)pyrazoles from 3-aminopyrazoles

IF 1.8 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY
Denis S. Koltun, Alexander D. Dilman
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引用次数: 0

Abstract

Pyrazoles bearing (2,3,5,6-tetrafluoropyridinyl)thio group were obtained from 3-aminopyrazoles. The reaction is performed by diazotization of starting amines followed by treatment of the intermediate diazonium salts with 2,3,5,6-tetrafluoropyridine-4-thiol and potassium carbonate. The method is best applied towards 4-substituted 3-aminopyrazoles.

Abstract Image

从 3-氨基吡唑合成 3-(2,3,5,6-四氟吡啶硫基)吡唑
含有 (2,3,5,6- 四氟吡啶基) 硫基的吡唑是从 3-氨基吡唑中获得的。该反应是先将起始胺重氮化,然后用 2,3,5,6-四氟吡啶-4-硫醇和碳酸钾处理中间重氮盐。该方法最适用于 4-取代的 3-氨基吡唑。
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来源期刊
Mendeleev Communications
Mendeleev Communications 化学-化学综合
CiteScore
3.00
自引率
21.10%
发文量
226
审稿时长
4-8 weeks
期刊介绍: Mendeleev Communications is the journal of the Russian Academy of Sciences, launched jointly by the Academy of Sciences of the USSR and the Royal Society of Chemistry (United Kingdom) in 1991. Starting from 1st January 2007, Elsevier is the new publishing partner of Mendeleev Communications. Mendeleev Communications publishes short communications in chemistry. The journal primarily features papers from the Russian Federation and the other states of the former USSR. However, it also includes papers by authors from other parts of the world. Mendeleev Communications is not a translated journal, but instead is published directly in English. The International Editorial Board is composed of eminent scientists who provide advice on refereeing policy.
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