Study on the Explosion Characteristics of CH4 with the Addition of Coal Spontaneous Combustion Gases

Yu Liu, Kai Wang, Mengmeng Luo, Jieqi Bai, Lin Wang and Fuchao Tian*, 
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Abstract

Combustible gases produced during the coal spontaneous combustion (CSC) process will cause hidden danger for mine safety. For studying the effect of the addition of CSC gas on CH4 explosion characteristics, a 20 L explosive device was adopted to obtain the explosion characteristics of CH4 (7%, 9.5%, and 11% in vol.) and CSC gas (0–2% in vol.) premixed fuel, and the effect of CSC gas on CH4 explosion characteristics was analyzed. Results show that for 7% CH4, CSC gas promotes the CH4 explosion. However, for 11% CH4, CSC gas inhibits the explosion of CH4. Based on the chemical reaction kinetics analysis, it indicates that adding CSC gas at different stages changes the sensitivity coefficients, which affects the concentration of active radicals. With the increase of CSC gas in CH4, the concentration of H increased, the concentration of O decreased, and the concentration of OH increased first and then decreased. The variations of O and OH are regarded to be the main reason for promoting the explosion of dilute CH4 and inhibiting the explosion of concentrated CH4. The variations of H, O, and OH indicate that the addition of the self-heating oxidation stage of CSC gas has a more evident effect on the CH4 explosion characteristics.

Abstract Image

加入煤自燃气体的 CH4 爆炸特性研究
煤炭自燃(CSC)过程中产生的可燃气体会给煤矿安全带来隐患。为研究CSC气体的加入对CH4爆炸特性的影响,采用20L爆破装置获得了CH4(体积分数为7%、9.5%和11%)与CSC气体(体积分数为0-2%)预混燃料的爆炸特性,并分析了CSC气体对CH4爆炸特性的影响。结果表明,对于 7% 的 CH4,CSC 气体会促进 CH4 的爆炸。然而,对于 11% 的 CH4,CSC 气体会抑制 CH4 的爆炸。根据化学反应动力学分析,在不同阶段加入 CSC 气体会改变灵敏度系数,从而影响活性自由基的浓度。随着 CH4 中 CSC 气体的增加,H 的浓度增加,O 的浓度降低,OH 的浓度先增加后降低。O和OH的变化被认为是促进稀CH4爆炸和抑制浓CH4爆炸的主要原因。H、O、OH 的变化表明,增加 CSC 气体的自热氧化阶段对 CH4 爆炸特性的影响更为明显。
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