Ti-catalyzed heterometathetical condensation of N-sulfinylamines into sulfurdiimines

IF 1.8 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Mendeleev Communications Pub Date : 2024-07-01 DOI:10.1016/j.mencom.2024.06.028

Nikolai S. Bushkov , Andrey V. Rumyantsev , Anton A. Zhizhin , Ivan A. Godovikov , Pavel A. Zhizhko , Dmitry N. Zarubin

引用次数: 0

Abstract

Well-defined silica-supported Ti imido complex (SiO)Ti(NBu^t)(Me₂Pyr)(Py)₂ (Me₂Pyr = 2,5-dimethyl- pyrrolyl) catalyzes condensation of N-sulfinylanilines into sulfurdiimines via the oxo/imido heterometathesis providing a convenient synthetic route to functionalized sulfurdiimines.

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钛催化 N-亚磺酰基胺与硫代亚胺的异金属缩合反应

定义明确的二氧化硅支撑 Ti 亚氨基配合物 (SiO)Ti(NBut)(Me2Pyr)(Py)2 （Me2Pyr = 2,5 二甲基吡咯基）通过氧化/亚氨基异构反应催化 N-亚磺酰苯胺缩合成硫代二亚胺，为功能化硫代二亚胺提供了一条便捷的合成路线。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Mendeleev Communications 化学-化学综合

CiteScore

3.00

自引率

21.10%

发文量

226

审稿时长

4-8 weeks

期刊介绍： Mendeleev Communications is the journal of the Russian Academy of Sciences, launched jointly by the Academy of Sciences of the USSR and the Royal Society of Chemistry (United Kingdom) in 1991. Starting from 1st January 2007, Elsevier is the new publishing partner of Mendeleev Communications. Mendeleev Communications publishes short communications in chemistry. The journal primarily features papers from the Russian Federation and the other states of the former USSR. However, it also includes papers by authors from other parts of the world. Mendeleev Communications is not a translated journal, but instead is published directly in English. The International Editorial Board is composed of eminent scientists who provide advice on refereeing policy.