Anticorrosive performance of piperidinium-based ionic liquid on 6061 aluminium alloy in HCl medium

IF 1.9 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY
Namitha Kedimar, Padmalatha Rao, Suma A Rao
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Abstract

Potentiodynamic polarization (PDP) and electrochemical impedance spectroscopy methods were used to investigate the inhibitory effects of 1-methyl-1-propyl-piperidinium bromide (MPPB) on the corrosion inhibition of 6061 aluminium alloy in the presence of 0.01 M HCl. The results of PDP studies indicate that MPPB behaved as a mixed inhibitor. The inductive loop in the Nyquist plot implies the adsorption of MPPB on the surface of 6061 aluminium alloy. Scanning electron microscope and atomic force microscopic analysis indicated the adsorption of MPPB on the surface of 6061 aluminium alloy by smooth surface in the presence of MPPB. The percentage composition of aluminium is found to be more in the presence of MPPB than in the absence of MPPB in a corrosive medium, which implies adsorption of MPPB on 6061 aluminium alloy. From PDP studies, it is evident that MPPB gave a maximum inhibition efficiency of 73.95% in 0.01 M HCl for 400 ppm of MPPB at 303 K.

Abstract Image

Abstract Image

哌啶基离子液体在盐酸介质中对 6061 铝合金的防腐性能
摘要 采用电动力极化(PDP)和电化学阻抗谱方法研究了1-甲基-1-丙基哌啶溴化物(MPPB)在0.01 M HCl存在下对6061铝合金的缓蚀作用。PDP 研究结果表明,MPPB 是一种混合抑制剂。奈奎斯特图中的感应环意味着 MPPB 吸附在 6061 铝合金表面。扫描电子显微镜和原子力显微镜分析表明,在 MPPB 存在的情况下,6061 铝合金表面光滑,表明表面吸附了 MPPB。在腐蚀性介质中,有 MPPB 存在时的铝成分百分比高于无 MPPB 存在时的百分比,这意味着 6061 铝合金表面吸附了 MPPB。从 PDP 研究中可以看出,在 303 K 的 0.01 M HCl 溶液中,对于 400 ppm 的 MPPB,MPPB 的最大抑制效率为 73.95%。
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来源期刊
Bulletin of Materials Science
Bulletin of Materials Science 工程技术-材料科学:综合
CiteScore
3.40
自引率
5.60%
发文量
209
审稿时长
11.5 months
期刊介绍: The Bulletin of Materials Science is a bi-monthly journal being published by the Indian Academy of Sciences in collaboration with the Materials Research Society of India and the Indian National Science Academy. The journal publishes original research articles, review articles and rapid communications in all areas of materials science. The journal also publishes from time to time important Conference Symposia/ Proceedings which are of interest to materials scientists. It has an International Advisory Editorial Board and an Editorial Committee. The Bulletin accords high importance to the quality of articles published and to keep at a minimum the processing time of papers submitted for publication.
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