Crystal structure of bis(β-alaninium) tetrabromidoplumbate

IF 0.5 Q4 CRYSTALLOGRAPHY

Acta Crystallographica Section E: Crystallographic Communications Pub Date : 2024-09-01 DOI:10.1107/S2056989024007722

Gayane S. Tonoyan , Gerald Giester , Vahram V. Ghazaryan , Ruben Yu. Chilingaryan , Arthur A. Margaryan , Artak H. Mkrtchyan , Aram M. Petrosyan

引用次数: 0

Abstract

This work focused on characterizing the structure from a stereochemical point of view, discussing the Pb^II character. The XRD data were collected at 200 K.

The title compound, poly[bis(β-alaninium) [[dibromidoplumbate]-di-μ-dibromido]] {(C₂H₈NO₂)₂[PbBr₄]}_n or (β-AlaH)₂PbBr₄, crystallizes in the monoclinic space group P2₁/n. The (PbBr₄)²⁻ anion is located on a general position and has a two-dimensional polymeric structure. The Pb center is holodirected. The supramolecular network is mainly based on O—H⋯Br, N—H⋯Br and N—H⋯O hydrogen bonds.

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双（β-丙氨酸）四溴锑酸盐晶体结构

标题化合物聚[双（β-丙氨酸）[[二溴铌酸盐]-二-μ-二溴]] {(C2H8NO2)2[PbBr4]} n 或 (β-AlaH)2PbBr4{(C2H8NO2)2[PbBr4]}n或 (β-AlaH)2PbBr4 在单斜空间群 P21/n 中结晶。(PbBr4)2- 阴离子位于一般位置，具有二维聚合结构。铅中心是全向的。超分子网络主要以 O-H...Br、N-H...Br 和 N-H...O 氢键为基础。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Acta Crystallographica Section E: Crystallographic Communications Chemistry-Chemistry (all)

CiteScore

1.90

自引率

0.00%

发文量

351

审稿时长

3 weeks

期刊介绍： Acta Crystallographica Section E: Crystallographic Communications is the IUCr''s open-access structural communications journal. It provides a fast, simple and easily accessible publication mechanism for crystal structure determinations of inorganic, metal-organic and organic compounds. The electronic submission, validation, refereeing and publication facilities of the journal ensure rapid and high-quality publication of fully validated structures. The primary article category is Research Communications; these are peer-reviewed articles describing one or more structure determinations with appropriate discussion of the science.

Crystal structure of bis­(β-alaninium) tetra­bromidoplumbate

Abstract

Crystal structure of bis(β-alaninium) tetrabromidoplumbate