Study on mechanical properties and damage characteristics of acid corrosion in granite based on NMR technology

Abstract

In acidic environments, rock masses are frequently subjected to severe chemical corrosion, resulting in the initiation of numerous geological engineering disasters. This study aimed to collect physical and mechanical parameters of granite exposed to prolonged acid corrosion and analyze fracture characteristics using acoustic emission (AE) techniques. Additionally, it examined the evolution of pore structure and damage mechanisms through the use of low-field nuclear magnetic resonance (NMR) and fractal theory. The results demonstrate a monotonic decrease in mass, volume, density, P-wave velocity, and S-wave velocity of granite with increasing corrosion time. Particularly notable is the phased reduction observed in uniaxial compressive strength and elastic modulus. The transition from brittle to ductile failure in corroded granite is accompanied by a gradual decrease in internal fracture strength. The trend in the correlation dimension reveals the relationship between the formation time of the main fracture surface and the pore structure. Additionally, total porosity and macropores (D, Da) exhibit significant fractal characteristics. The fractal dimension correlates positively with the damage variable and inversely with uniaxial compressive strength and elastic modulus. This indicates that more severe pore structure damage leads to a higher fractal dimension and lower mechanical performance. Among these, Da demonstrates higher sensitivity in characterizing rock mechanical properties. These findings provide important basis for evaluating the stability of granite geotechnical engineering in acidic environments.