Chromium gradient stainless steels with simultaneous high strength, ductility, and corrosion-resistant: In-depth study of continuous hardening mechanisms

Abstract

Cr-rich stainless steel sheets exhibit superior corrosion resistance but low ductility, which presents a trade-off between fabrication complexity and performance of the materials in multiple industrial applications, such as marine equipment and microreactors. By transitioning the Cr-rich (30 wt.% Cr) stainless steel component to SS 316 L with a smooth composition gradient in the thickness direction, the intrinsic homogeneous elongation of the Cr-rich layer was increased by 260 % while maintaining the naturally high corrosion resistance (100 %) and retaining most of the strength (more than 80 %). By employing in-situ tensile testing and electron backscatter diffraction analysis, it was revealed that the Cr-rich layer in the gradient structure underwent a profound deformation mechanism, including significant heterogeneous deformation-induced hardening and grain reorientation induced by multiplication and accumulation of geometrically necessary dislocations, in such a way to enable a substantial plastic strain and thereby retarding the occurrence of fracture. The proportion of the Cr-rich layer makes a significant impact on the magnitude of the strain gradient in the gradient specimens, therefore affecting the increment of density of geometrically necessary dislocations. The critical proportion value of the Cr-rich layer is found to be around 22 %. Before and after the critical value the gradient specimens showed different sensitivities to the proportion. This discovery underlines the significance of intrinsic plasticity in low-ductility metals and the role of compositional gradient materials in enhancing strength and ductility.