Comparison of nano-zinc oxide or calcium chloride incorporated polyvinyl alcohol/chitosan/anthocyanin films for active and intelligent packaging

IF 2.2 4区 化学 Q3 CHEMISTRY, PHYSICAL
Yangyang Qi, Yana Li
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引用次数: 0

Abstract

Polyvinyl alcohol (PVA) and chitosan (CS) were mixed with purple tomato anthocyanins (PTA), and then nano zinc oxide (nano-ZnO) or calcium chloride (CaCl2) were added to prepare PVA/CS/PTA/ nano-ZnO (PCP-ZnO) or PVA/CS/PTA/CaCl2 (PCP-CaCl2) films. The effects of nano-ZnO and CaCl2 on the morphology, pH response, color stability, color reversibility, antibacterial activity, antioxidant activity, mechanical properties, water vapor permeability and UV absorption characteristics of films were studied. In addition, its application in intelligent packaging to monitor the freshness of pork was also studied. It was found that both nano-ZnO and CaCl2 can reduce the transmittance of the film in the visible light region, and the film with addition of nano-ZnO was more sensitive to pH. During the 14 day storage period, the film modified with CaCl2 exhibited better color stability. SEM images indicate that the addition of nano-ZnO or CaCl2 alters the microstructure of the film. The mechanical, antibacterial and antioxidant properties and also the application as freshness indicator of PCP-CaCl2 film were superior to those of PCP-ZnO film. Those indicated that the prepared PCP-CaCl2 film is a potential candidate for active and intelligent packaging applications.

Graphical abstract

Abstract Image

用于活性智能包装的纳米氧化锌或氯化钙聚乙烯醇/壳聚糖/花青素薄膜的比较
将聚乙烯醇(PVA)和壳聚糖(CS)与紫色番茄花青素(PTA)混合,然后加入纳米氧化锌(Nano-ZnO)或氯化钙(CaCl2)制备PVA/CS/PTA/纳米氧化锌(PCP-ZnO)或PVA/CS/PTA/CaCl2(PCP-CaCl2)薄膜。研究了纳米氧化锌和 CaCl2 对薄膜形态、pH 值响应、颜色稳定性、颜色可逆性、抗菌活性、抗氧化活性、机械性能、水蒸气渗透性和紫外线吸收特性的影响。此外,还研究了其在监测猪肉新鲜度的智能包装中的应用。研究发现,纳米氧化锌和 CaCl2 都能降低薄膜在可见光区域的透射率,而添加了纳米氧化锌的薄膜对 pH 值更为敏感。在 14 天的储存期间,用 CaCl2 修饰的薄膜表现出更好的颜色稳定性。扫描电镜图像表明,添加纳米氧化锌或 CaCl2 改变了薄膜的微观结构。五氯苯酚-氯化钙薄膜的机械性能、抗菌性能、抗氧化性能以及作为新鲜度指示剂的应用均优于五氯苯酚-氧化锌薄膜。这表明所制备的五氯苯酚-氯化钙薄膜是活性和智能包装应用的潜在候选材料。
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来源期刊
Colloid and Polymer Science
Colloid and Polymer Science 化学-高分子科学
CiteScore
4.60
自引率
4.20%
发文量
111
审稿时长
2.2 months
期刊介绍: Colloid and Polymer Science - a leading international journal of longstanding tradition - is devoted to colloid and polymer science and its interdisciplinary interactions. As such, it responds to a demand which has lost none of its actuality as revealed in the trends of contemporary materials science.
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