{"title":"Comparison of nano-zinc oxide or calcium chloride incorporated polyvinyl alcohol/chitosan/anthocyanin films for active and intelligent packaging","authors":"Yangyang Qi, Yana Li","doi":"10.1007/s00396-024-05295-2","DOIUrl":null,"url":null,"abstract":"<div><p>Polyvinyl alcohol (PVA) and chitosan (CS) were mixed with purple tomato anthocyanins (PTA), and then nano zinc oxide (nano-ZnO) or calcium chloride (CaCl<sub>2</sub>) were added to prepare PVA/CS/PTA/ nano-ZnO (PCP-ZnO) or PVA/CS/PTA/CaCl<sub>2</sub> (PCP-CaCl<sub>2</sub>) films. The effects of nano-ZnO and CaCl<sub>2</sub> on the morphology, pH response, color stability, color reversibility, antibacterial activity, antioxidant activity, mechanical properties, water vapor permeability and UV absorption characteristics of films were studied. In addition, its application in intelligent packaging to monitor the freshness of pork was also studied. It was found that both nano-ZnO and CaCl<sub>2</sub> can reduce the transmittance of the film in the visible light region, and the film with addition of nano-ZnO was more sensitive to pH. During the 14 day storage period, the film modified with CaCl<sub>2</sub> exhibited better color stability. SEM images indicate that the addition of nano-ZnO or CaCl<sub>2</sub> alters the microstructure of the film. The mechanical, antibacterial and antioxidant properties and also the application as freshness indicator of PCP-CaCl<sub>2</sub> film were superior to those of PCP-ZnO film. Those indicated that the prepared PCP-CaCl<sub>2</sub> film is a potential candidate for active and intelligent packaging applications.</p><h3>Graphical abstract</h3>\n<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":520,"journal":{"name":"Colloid and Polymer Science","volume":"302 11","pages":"1711 - 1723"},"PeriodicalIF":2.2000,"publicationDate":"2024-07-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Colloid and Polymer Science","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s00396-024-05295-2","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Polyvinyl alcohol (PVA) and chitosan (CS) were mixed with purple tomato anthocyanins (PTA), and then nano zinc oxide (nano-ZnO) or calcium chloride (CaCl2) were added to prepare PVA/CS/PTA/ nano-ZnO (PCP-ZnO) or PVA/CS/PTA/CaCl2 (PCP-CaCl2) films. The effects of nano-ZnO and CaCl2 on the morphology, pH response, color stability, color reversibility, antibacterial activity, antioxidant activity, mechanical properties, water vapor permeability and UV absorption characteristics of films were studied. In addition, its application in intelligent packaging to monitor the freshness of pork was also studied. It was found that both nano-ZnO and CaCl2 can reduce the transmittance of the film in the visible light region, and the film with addition of nano-ZnO was more sensitive to pH. During the 14 day storage period, the film modified with CaCl2 exhibited better color stability. SEM images indicate that the addition of nano-ZnO or CaCl2 alters the microstructure of the film. The mechanical, antibacterial and antioxidant properties and also the application as freshness indicator of PCP-CaCl2 film were superior to those of PCP-ZnO film. Those indicated that the prepared PCP-CaCl2 film is a potential candidate for active and intelligent packaging applications.
期刊介绍：
Colloid and Polymer Science - a leading international journal of longstanding tradition - is devoted to colloid and polymer science and its interdisciplinary interactions. As such, it responds to a demand which has lost none of its actuality as revealed in the trends of contemporary materials science.
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