Spectral Properties of Tolane and Its Supramolecular Complexes in Solution and Silicate Hydrogel
IF 1.8
3区 化学
Q3 CHEMISTRY, INORGANIC & NUCLEAR
引用次数: 0
Abstract
The complexation process of tolane and α-cyclodextrin in water, aqueous-ethanol solution, and silicate hydrogel based on tetrakis(2-hydroxyethyl)orthosilicate was studied. The complex formation in solutions were confirmed by electron and 1H NMR spectroscopy, and the stability constant of the complex was determined using spectrofluorimetric titration (log K1 : 1 = 1.5). The preservation of the inclusion complex during the preparation of the gel was confirmed by electron spectroscopy.
溶液和硅酸盐水凝胶中的托兰及其超分子复合物的光谱特性
摘要 研究了甲苯与α-环糊精在水、乙醇水溶液和基于四（2-羟乙基）原硅酸盐的硅酸盐水凝胶中的络合过程。电子和 1H NMR 光谱证实了溶液中络合物的形成，并利用分光荧光滴定法测定了络合物的稳定常数（log K1 : 1 = 1.5）。电子能谱证实了在凝胶制备过程中包合复合物的保存情况。
本文章由计算机程序翻译，如有差异，请以英文原文为准。
求助全文
约1分钟内获得全文
求助全文
来源期刊
Russian Journal of Inorganic Chemistry
化学-无机化学与核化学
CiteScore
3.10
自引率
38.10%
发文量
237
审稿时长
3 months
期刊介绍：
Russian Journal of Inorganic Chemistry is a monthly periodical that covers the following topics of research: the synthesis and properties of inorganic compounds, coordination compounds, physicochemical analysis of inorganic systems, theoretical inorganic chemistry, physical methods of investigation, chemistry of solutions, inorganic materials, and nanomaterials.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
