Green synthesized silver and zinc doped hydroxyapatite photocatalysts to remove methylene blue and Rhodamine B dyes from industrial wastewater

Abstract

The present study focussed on the Scallop Sea shell waste utilized Hydroxyapatite and green synthesis of Canna indica leaf extracted Zinc (Zn) and Silver (Ag) doped Hydroxyapatite (HAp) formed by microwave irradiation method which is respectively represented as H, CIZH, and CIAH. The functional and structural characterizations (FTIR and XRD) of products confirm that the formed material was Hydroxyapatite due to the existence of characteristic absorption peaks and diffracted planes. The structural parameters such as average crystallite size, micro-strain (ε), dislocation density (δ), and particle size of the H, CIZH, and CIAH were calculated and the average Crystallite size are 42, 40, and 31nm. The morphology of the H, CIZH, and CIAH were assessed through FE-SEM and HR-TEM which could be majorly hexagonal-like (well distinct, and cluster of few rods). The EDAX spectrum and mapping confirmed the presence of chemical compositions of studied products. The anti-bacterial activities of studied products were assessed against Escherichia coli and Staphylococcus aureus, which exhibit good antibacterial activity. The photocatalytic activity of H, CIZH, and CIAH was examined against Methylene blue (MB) and Rhodamine B (RhB) dyes under UV light illumination. The degradation efficiency (%) of H, CIZH, and CIAH against MB and RhB dye were 58, 63, and 71%, and 58, 82 and 90%, respectively. A possible mechanism of the photocatalytic activity against the above-mentioned dyes is proposed. Thus, the present CIAH photocatalyst could be effective in degrading the wastewater.