Study of Intermolecular Interaction by Ultrasonic Measurements of 1-Butanol-Pyridine and Toluene-Pyridine at 303.15 To 323.15 K and Statistical Analysis of Liquid State Theories

Samir M. Bagade, Ankush W Wakode
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Abstract

The experimental parameters measured in binary liquid mixtures, such as ultrasonic velocity (u) and density (ρ) containing 1-butanol-pyridine and toluene-pyridine across the full range of composition at different temperatures 303.15K to 323.15K, are used to evaluate acoustical parameters. The parameters are also theoretically calculated by using the Jacobson free length theory (flt) and Kalidoss revised free length theory (rflt). The statistical analysis of the liquid state theories has been done by applying chi-square (χ2) test. The findings were explained in terms of the liquid state theories that applied to binary liquid mixes as well as molecular interaction.
在 303.15 至 323.15 K 温度下通过超声波测量 1-丁醇-吡啶和甲苯-吡啶来研究分子间相互作用以及液态理论的统计分析
在含有 1-丁醇-吡啶和甲苯-吡啶的二元液体混合物中测得的实验参数,如在 303.15K 至 323.15K 不同温度下的全成分范围内的超声波速度 (u) 和密度 (ρ),用于评估声学参数。这些参数还通过雅各布森自由长度理论(flt)和卡利多斯修正自由长度理论(rflt)进行了理论计算。液态理论的统计分析采用了卡方检验(χ2)。研究结果从适用于二元液体混合物的液态理论以及分子相互作用的角度进行了解释。
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