An investigation into the effect of anode platinum loading on Direct Methanol Fuel Cell performance

Karthikeyan Palaniswamy
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Abstract

Direct methanol fuel cells can utilize a liquid methanol fuel directly, without the need for prior reformation. This ability is highly advantageous when compared with other fuel cell technologies, which require pure hydrogen as a fuel source. An investigation was carried out to try and optimize the anode platinum loading using both Pt-NiTiO3 and Pt-Ru based electrocatalysts by determining a point of diminishing performance returns. The results showed continued performance improvement as anode platinum loading increased for the Pt-NiTiO3 catalyst, likely as a result of the methanol oxidation capabilities of NiTiO3. Whereas, for Pt-Ru based catalysts, an optimum point was found at 0.66 mgPt cm-2.
阳极铂负载对直接甲醇燃料电池性能影响的研究
直接甲醇燃料电池可直接利用液态甲醇燃料,无需事先进行转化。与其他需要纯氢作为燃料来源的燃料电池技术相比,这种能力具有极大的优势。通过确定性能回报递减点,对使用基于 Pt-NiTiO3 和 Pt-Ru 的电催化剂的阳极铂负载进行了研究和优化。结果表明,随着阳极铂负载量的增加,Pt-NiTiO3 催化剂的性能持续改善,这可能是 NiTiO3 具有甲醇氧化能力的结果。而以铂-钌为基础的催化剂在 0.66 毫克铂 cm-2 时达到了最佳点。
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