Up-Conversion Luminescence and Optical Temperature Sensing of Tb3+, Yb3+, Er3+ Doped (Gd, Y, Lu)2O2S Series Phosphors

Di Shao, Liping Lu, Haiying Sun, Z. Bai
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Abstract

The phase analysis, luminous intensity, and luminescence lifetime of different doping concentrations of Tb3+ (1 mol % - 11 mol %), Yb3+ (9 mol % - 54 mol %), Er3+ (0.1 mol % - 1.1 mol %) ions and different introduction concentrations of Y3+ (1 mol % - 6 mol %) and Lu3+ (0.5 mol % - 3 mol %) of Gd2O2S series phosphors were studied systematically. In addition, the energy transfer model of Tb3+-Yb3+-Er3+ was established by analyzing the changes of luminous intensity and luminescence lifetime of novel (Gd, Y, Lu)2O2S phosphors co-doped Tb3+, Yb3+ and Er3+ which were prepared by the coprecipitation-high temperature solid-state reaction method., The luminescence intensity ratio equations of the sample excited by 980 nm was obtained at 313-553 K. And the absolute sensitivities were 0.0033 (313 K). This work is of reference value to the study of the mechanism of up-conversion system.
掺杂 Tb3+、Yb3+、Er3+(Gd、Y、Lu)2O2S 系列荧光粉的上转换发光和光学温度传感
系统研究了 Gd2O2S 系列荧光粉中不同掺杂浓度的 Tb3+ (1 mol % - 11 mol %)、Yb3+ (9 mol % - 54 mol %)、Er3+ (0.1 mol % - 1.1 mol %) 离子以及不同引入浓度的 Y3+ (1 mol % - 6 mol %) 和 Lu3+ (0.5 mol % - 3 mol %)的相分析、发光强度和发光寿命。此外,通过分析共沉淀-高温固态反应法制备的新型(Gd、Y、Lu)2O2S 共掺杂 Tb3+、Yb3+ 和 Er3+荧光粉的发光强度和发光寿命的变化,建立了 Tb3+-Yb3+-Er3+的能量传递模型。这项工作对研究上转换系统的机理具有参考价值。
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