{"title":"Study of synergistic behavior during bituminous coal-cow manure co-gasification: The role of intrinsic AAEM and organic matter","authors":"Hongqiao Lu, Meng Ma, Juntao Wei, Yonghui Bai, Peng Lv, Jiaofei Wang, Xudong Song, Guanghua Lu, Guangsuo Yu","doi":"10.1007/s40789-024-00694-w","DOIUrl":null,"url":null,"abstract":"<p>Co-thermal chemical conversion of coal and biomass is one of the important ways to realize efficient and clean utilization of coal. In this study, a typical Ningdong coal-Yangchangwan bituminous coal and cow manure were used to study the synergistic effect of intrinsic alkali, alkaline earth metals (AAEM) and organic matter on the co-gasification of coal and biomass by thermogravimetry analyzer (TG). The results showed that AAEM had obvious synergistic promotion effect on the gasification of a bituminous coal-cow manure mixture in the isothermal gasification (1000 ℃), whereas the organic matter will show the opposite effect on the process. To further investigate the effect of organic matter on the gasification process, the influence of organic matter on non-isothermal (25-1000 ℃) gasification reaction was investigated with heating rate of 10 ℃ /min, the kinetic parameters of the gasification reaction were obtained by Coats-Redfern method. The increase of biomass mass fraction in the sample facilitates the migration of alkali metals from the material to the solid phase. The possible mechanism of the synergistic effect of intrinsic AAEM/organic matter on the co-gasification process was proposed.</p>","PeriodicalId":53469,"journal":{"name":"International Journal of Coal Science & Technology","volume":null,"pages":null},"PeriodicalIF":6.9000,"publicationDate":"2024-07-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Coal Science & Technology","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1007/s40789-024-00694-w","RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
引用次数: 0
Abstract
Co-thermal chemical conversion of coal and biomass is one of the important ways to realize efficient and clean utilization of coal. In this study, a typical Ningdong coal-Yangchangwan bituminous coal and cow manure were used to study the synergistic effect of intrinsic alkali, alkaline earth metals (AAEM) and organic matter on the co-gasification of coal and biomass by thermogravimetry analyzer (TG). The results showed that AAEM had obvious synergistic promotion effect on the gasification of a bituminous coal-cow manure mixture in the isothermal gasification (1000 ℃), whereas the organic matter will show the opposite effect on the process. To further investigate the effect of organic matter on the gasification process, the influence of organic matter on non-isothermal (25-1000 ℃) gasification reaction was investigated with heating rate of 10 ℃ /min, the kinetic parameters of the gasification reaction were obtained by Coats-Redfern method. The increase of biomass mass fraction in the sample facilitates the migration of alkali metals from the material to the solid phase. The possible mechanism of the synergistic effect of intrinsic AAEM/organic matter on the co-gasification process was proposed.
期刊介绍:
The International Journal of Coal Science & Technology is a peer-reviewed open access journal that focuses on key topics of coal scientific research and mining development. It serves as a forum for scientists to present research findings and discuss challenging issues in the field.
The journal covers a range of topics including coal geology, geochemistry, geophysics, mineralogy, and petrology. It also covers coal mining theory, technology, and engineering, as well as coal processing, utilization, and conversion. Additionally, the journal explores coal mining environment and reclamation, along with related aspects.
The International Journal of Coal Science & Technology is published with China Coal Society, who also cover the publication costs. This means that authors do not need to pay an article-processing charge.