Electron Diffraction Structure Analysis of the Amorphous Polytetrafluoroethylene Film

IF 0.6 4区 材料科学 Q4 CRYSTALLOGRAPHY
A. K. Kulygin, N. V. Sadovskaya, A. S. Avilov, O. I. Vasin
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引用次数: 0

Abstract

A thin amorphous fluoroplast (polytetrafluoroethylene) film has been obtained and studied by methods of electron diffraction structure analysis. The previously developed method of constructing atomic radial distribution functions from electron diffraction patterns of amorphous structures, which is based on determining the normalization factor by varying the thermal parameter, was applied. The possibility of applying this technique is shown, and its necessary adaptation for the investigated polytetrafluoroethylene sample is performed with allowance for its not quite usual amorphous structure due to the rigid helical conformation of polymer chains …–CF2–…, which does not allow us to speak about complete absence of the long-range order in the arrangement of atoms along the helix axis. Measurements were performed using the developed registration system on an EMR-102 electron diffractometer.

Abstract Image

无定形聚四氟乙烯薄膜的电子衍射结构分析
摘要 通过电子衍射结构分析方法获得并研究了一种非晶氟塑料(聚四氟乙烯)薄膜。应用了以前开发的从非晶结构的电子衍射图中构建原子径向分布函数的方法,该方法的基础是通过改变热参数来确定归一化系数。该方法显示了应用该技术的可能性,并对所研究的聚四氟乙烯样品进行了必要的调整,同时考虑到由于聚合物链......-CF2-......的刚性螺旋构象而造成的不太常见的无定形结构,因此不能说沿螺旋轴的原子排列完全不存在长程有序性。测量是在 EMR-102 电子衍射仪上使用开发的登记系统进行的。
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来源期刊
Crystallography Reports
Crystallography Reports 化学-晶体学
CiteScore
1.10
自引率
28.60%
发文量
96
审稿时长
4-8 weeks
期刊介绍: Crystallography Reports is a journal that publishes original articles short communications, and reviews on various aspects of crystallography: diffraction and scattering of X-rays, electrons, and neutrons, determination of crystal structure of inorganic and organic substances, including proteins and other biological substances; UV-VIS and IR spectroscopy; growth, imperfect structure and physical properties of crystals; thin films, liquid crystals, nanomaterials, partially disordered systems, and the methods of studies.
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