Mixed-Ligand Chloride Complex of Co(II) withE-2-(((4-Iodophenyl)Imino)Methyl)Phenol: Crystal Structure and Features of Halogen Bonding in a Solid

IF 16.4 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Accounts of Chemical Research Pub Date : 2024-07-26 DOI:10.1134/S0022476624070126

S. A. Adonin, P. A. Abramov, A. S. Zaguzin, A. S. Novikov

引用次数: 0

Abstract

Neutral complex [L₂CoCl₂] is obtained by the reaction of cobalt(II) chloride with E-(((4-iodophenyl)imino)methyl)phenol (L), and its structure is studied by single crystal X-ray diffraction. The structure contains I⋯Cl halogen bonds whose energies are estimated by quantum chemical calculations.

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Co(II)与 E-2-(((4-碘苯基)氨基)甲基)苯酚的混合配体氯化物配合物：晶体结构和固体中卤素键合的特征

摘要通过氯化钴（II）与 E-(((4-碘苯基)亚氨基)甲基)苯酚（L）反应得到中性络合物 [L2CoCl2]，并通过单晶 X 射线衍射对其结构进行了研究。该结构包含 I⋯Cl 卤素键，其能量是通过量子化学计算估算的。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Accounts of Chemical Research 化学-化学综合

CiteScore

31.40

自引率

1.10%

发文量

312

审稿时长

2 months

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