Phosphorus-mediated hydrogenation catalysis

IF 19.2 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Nature chemistry Pub Date : 2024-07-24 DOI:10.1038/s41557-024-01588-9

Josh Abbenseth

引用次数: 0

Abstract

Hydrogenation catalysis is commonly associated with (noble) transition metals that undergo oxidative addition of H2 and subsequently transfer hydrogen atoms to unsaturated substrates. Now, a geometrically constrained phosphenium cation can facilitate both of these challenging transformations.

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磷介导的氢化催化。

氢化催化通常与（惰性）过渡金属有关，这些金属可进行 H2 的氧化加成，然后将氢原子转移到不饱和底物上。现在，一种受几何约束的膦阳离子可以促进这两种具有挑战性的转化。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Nature chemistry 化学-化学综合

CiteScore

29.60

自引率

1.40%

发文量

226

审稿时长

1.7 months

期刊介绍： Nature Chemistry is a monthly journal that publishes groundbreaking and significant research in all areas of chemistry. It covers traditional subjects such as analytical, inorganic, organic, and physical chemistry, as well as a wide range of other topics including catalysis, computational and theoretical chemistry, and environmental chemistry. The journal also features interdisciplinary research at the interface of chemistry with biology, materials science, nanotechnology, and physics. Manuscripts detailing such multidisciplinary work are encouraged, as long as the central theme pertains to chemistry. Aside from primary research, Nature Chemistry publishes review articles, news and views, research highlights from other journals, commentaries, book reviews, correspondence, and analysis of the broader chemical landscape. It also addresses crucial issues related to education, funding, policy, intellectual property, and the societal impact of chemistry. Nature Chemistry is dedicated to ensuring the highest standards of original research through a fair and rigorous review process. It offers authors maximum visibility for their papers, access to a broad readership, exceptional copy editing and production standards, rapid publication, and independence from academic societies and other vested interests. Overall, Nature Chemistry aims to be the authoritative voice of the global chemical community.