Functionalization of Boranes through Thiol/Oxygen Catalysis†

IF 5.5 1区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chinese Journal of Chemistry Pub Date : 2024-07-17 DOI:10.1002/cjoc.202400494

Hongyi Tao, Hairong Lyu

引用次数: 0

Abstract

A greener and more convenient alternative to traditional methods for the generation of thiyl radical as hydrogen atom transfer (HAT) catalyst is developed, using molecular oxygen to oxidize thiol without the need for chemical initiators or light irradiation. The thiol/oxygen catalysis enables selective and efficient difunctionalization of borane.

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通过硫醇/氧催化作用使硼烷官能化†。

综合摘要与传统的生成硫基作为氢原子转移（HAT）催化剂的方法相比，本研究开发出了一种更环保、更方便的替代方法，即利用分子氧氧化硫醇，而无需化学引发剂或光照。硫醇/氧催化实现了硼烷选择性和高效的双官能化。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Chinese Journal of Chemistry 化学-化学综合

CiteScore

8.80

自引率

14.80%

发文量

422

审稿时长

1.7 months

期刊介绍： The Chinese Journal of Chemistry is an international forum for peer-reviewed original research results in all fields of chemistry. Founded in 1983 under the name Acta Chimica Sinica English Edition and renamed in 1990 as Chinese Journal of Chemistry, the journal publishes a stimulating mixture of Accounts, Full Papers, Notes and Communications in English.