Influence of rolling reduction on corrosion behavior of WE43 alloy

IF 4.7 1区 材料科学 Q1 METALLURGY & METALLURGICAL ENGINEERING
Yong CAI , Yi-peng CHEN , Hong YAN , Zhi-wei SHAN , Yao-zong MAO , Rong-shi CHEN
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引用次数: 0

Abstract

The corrosion behavior of WE43 alloy with different rolling reductions (0%, 25%, 45%, and 80%) at 500 °C was investigated in 3.5 wt.% NaCl solution. The microstructure evolution of the rolled WE43 alloy was characterized in detail by means of optical microscopy (OM), transmission electron microscopy (TEM) and electron back-scattered diffraction (EBSD). The results show that with increasing reductions, basal texture is gradually enhanced and grain size gradually decreases. Only the alloy with 45% reduction exhibits dispersed dynamic precipitates. Immersion and electrochemical measurements demonstrate the decreasing order of the corrosion resistance of the rolled WE43 alloy: 45% reduction > 80% reduction > 25% reduction > 0 reduction. The best corrosion resistance of the WE43 alloy with 45% reduction is mainly related to a large number of finely dispersed precipitates, which are capable of promoting the formation of a compact corrosion product layer. The increased corrosion rate of the sample with 80% reduction is induced by the re-solution of the majority of precipitates into the matrix. The grain size, basal texture and deformation twins have a limited effect on the corrosion resistance of rolled WE43 alloy compared with the precipitates.

轧制还原对 WE43 合金腐蚀行为的影响
在 3.5 wt.% 的氯化钠溶液中,研究了不同轧制减薄率(0%、25%、45% 和 80%)的 WE43 合金在 500 °C 下的腐蚀行为。通过光学显微镜(OM)、透射电子显微镜(TEM)和电子背散射衍射(EBSD)对轧制后的 WE43 合金的微观结构演变进行了详细表征。结果表明,随着还原度的增加,基底纹理逐渐增强,晶粒尺寸逐渐减小。只有还原度为 45% 的合金才表现出分散的动态沉淀。浸泡和电化学测量结果表明,轧制的 WE43 合金的耐腐蚀性能依次递减:减薄率为 45%;减薄率为 80%;减薄率为 25%;减薄率为 0。减薄 45% 的 WE43 合金具有最佳耐腐蚀性能,这主要与大量细小分散的析出物有关,这些析出物能够促进形成致密的腐蚀产物层。大部分析出物重新溶解到基体中,导致减薄 80% 的样品腐蚀速率增加。与析出物相比,晶粒大小、基体纹理和变形孪晶对轧制的 WE43 合金的耐腐蚀性影响有限。
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来源期刊
CiteScore
7.40
自引率
17.80%
发文量
8456
审稿时长
3.6 months
期刊介绍: The Transactions of Nonferrous Metals Society of China (Trans. Nonferrous Met. Soc. China), founded in 1991 and sponsored by The Nonferrous Metals Society of China, is published monthly now and mainly contains reports of original research which reflect the new progresses in the field of nonferrous metals science and technology, including mineral processing, extraction metallurgy, metallic materials and heat treatments, metal working, physical metallurgy, powder metallurgy, with the emphasis on fundamental science. It is the unique preeminent publication in English for scientists, engineers, under/post-graduates on the field of nonferrous metals industry. This journal is covered by many famous abstract/index systems and databases such as SCI Expanded, Ei Compendex Plus, INSPEC, CA, METADEX, AJ and JICST.
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