{"title":"3D printed polymer-matrix loaded with graphene oxide","authors":"","doi":"10.1016/j.matlet.2024.137012","DOIUrl":null,"url":null,"abstract":"<div><p>This research deals with adding graphene oxide, resulting in a novel resin suitable for additive manufacturing technologies based on layer-by-layer photopolymerization. The mechanical and thermal properties demonstrate that the specimens manufactured with graphene oxide with low concentration achieve an excellent combination of strength and ductility. Graphene oxide highly influences the molecular dynamics of the polymeric matrix, modulating the glass transition and thermal stability so that it obtains a more elastic behavior or enhanced stiffness, depending on the concentration. The structural properties show that the structural disorders in the polymer matrix are due to variations in graphene oxide content, so graphene oxide embedded in the photopolymer resin did not produce relevant structural changes, form any covalent bond, or add new functional groups.</p></div>","PeriodicalId":384,"journal":{"name":"Materials Letters","volume":null,"pages":null},"PeriodicalIF":2.7000,"publicationDate":"2024-07-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Letters","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0167577X24011510","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
This research deals with adding graphene oxide, resulting in a novel resin suitable for additive manufacturing technologies based on layer-by-layer photopolymerization. The mechanical and thermal properties demonstrate that the specimens manufactured with graphene oxide with low concentration achieve an excellent combination of strength and ductility. Graphene oxide highly influences the molecular dynamics of the polymeric matrix, modulating the glass transition and thermal stability so that it obtains a more elastic behavior or enhanced stiffness, depending on the concentration. The structural properties show that the structural disorders in the polymer matrix are due to variations in graphene oxide content, so graphene oxide embedded in the photopolymer resin did not produce relevant structural changes, form any covalent bond, or add new functional groups.
期刊介绍：
Materials Letters has an open access mirror journal Materials Letters: X, sharing the same aims and scope, editorial team, submission system and rigorous peer review.
Materials Letters is dedicated to publishing novel, cutting edge reports of broad interest to the materials community. The journal provides a forum for materials scientists and engineers, physicists, and chemists to rapidly communicate on the most important topics in the field of materials.
Contributions include, but are not limited to, a variety of topics such as:
• Materials - Metals and alloys, amorphous solids, ceramics, composites, polymers, semiconductors
• Applications - Structural, opto-electronic, magnetic, medical, MEMS, sensors, smart
• Characterization - Analytical, microscopy, scanning probes, nanoscopic, optical, electrical, magnetic, acoustic, spectroscopic, diffraction
• Novel Materials - Micro and nanostructures (nanowires, nanotubes, nanoparticles), nanocomposites, thin films, superlattices, quantum dots.
• Processing - Crystal growth, thin film processing, sol-gel processing, mechanical processing, assembly, nanocrystalline processing.
• Properties - Mechanical, magnetic, optical, electrical, ferroelectric, thermal, interfacial, transport, thermodynamic
• Synthesis - Quenching, solid state, solidification, solution synthesis, vapor deposition, high pressure, explosive
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