Experimental Investigation of Thermal Runaway Characteristics of Large-Format Li(Ni0.8Co0.1Mn0.1)O2 Battery under Different Heating Powers and Areas

Jingru Huang, Zhuwei Fan, Chengshan Xu, Fachao Jiang, Xuning Feng
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Abstract

This study experimentally investigates the effects of different heating powers and areas on the jet behavior and thermal runaway (TR) of 75 Ah LiNi0.8Co0.1Mn0.1O2 pouch lithium-ion batteries (LIBs) in an open environment. TR, a critical safety concern for LIBs, can occur under overheating conditions. The TR behavior of LIBs was characterized by flame behavior, temperature characteristics, mass variation, jet dynamics, and residue formations. The results reveal that the heating power density primarily influences the time to initiate TR. Lower power densities extend the heating time and require higher energy to induce TR, thereby exerting a more considerable impact on the battery. The heating area predominantly affects the input energy and the extent of damage. Larger areas lead to more stable jet flames, consistent peak temperatures ranging between 1000 °C and 1300 °C, and mass loss ratios ranging from 44% to 53% compared to 43% to 47% for small-area heaters. These findings provide references for the safety design of battery assemblies and the prevention of TR propagation, contributing to the safer monitoring of LIBs.
不同加热功率和面积下大规格锂(Ni0.8Co0.1Mn0.1)O2 电池热失控特性的实验研究
本研究通过实验研究了不同加热功率和面积对开放环境中 75 Ah LiNi0.8Co0.1Mn0.1O2 袋装锂离子电池(LIB)的喷射行为和热失控(TR)的影响。失控是锂离子电池的一个重要安全问题,可能在过热条件下发生。研究人员通过火焰行为、温度特性、质量变化、喷射动态和残留物形成等方面对锂离子电池的 TR 行为进行了表征。结果表明,加热功率密度主要影响启动 TR 的时间。功率密度越低,加热时间越长,诱发 TR 所需的能量越高,从而对电池产生的影响越大。加热区域主要影响输入能量和损坏程度。面积越大,喷射火焰越稳定,峰值温度在 1000 °C 至 1300 °C 之间,质量损失率在 44% 至 53% 之间,而小面积加热器的质量损失率为 43% 至 47%。这些发现为电池组件的安全设计和防止 TR 传播提供了参考,有助于更安全地监测 LIB。
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