Isotopic shift analysis of GdO by LAMIS

IF 3.2 2区化学 Q1 SPECTROSCOPY

Spectrochimica Acta Part B: Atomic Spectroscopy Pub Date : 2024-07-14 DOI:10.1016/j.sab.2024.106993

M. Gaft , L. Nagli , J. Fernandes , V. Gardette , Y. Raichlin , V. Motto-Ros

引用次数: 0

Abstract

LAMIS is a known technique for isotopic shift analysis of light elements, such as B, C, etc. Its application for heavy molecules has been studied less. We proved that vibrational and rotational transitions A(1–0), A(1–2), and A(2–1) of GdO in Laser-Induced Plasma exhibit apparent differences between natural GdO, ¹⁵⁶GdO, and ¹⁵⁸GdO emissions. The absolute values are in the 0.4–0.5 cm⁻¹ range. Besides its adequate spectral resolution, the Demon HR Double Echelle Monochromator proved its sensitivity for isotopic analysis of Rare Earth Elements.

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利用 LAMIS 对氧化钆进行同位素位移分析

LAMIS 是一种已知的轻元素（如 B、C 等）同位素偏移分析技术。对其在重分子中的应用研究较少。我们证明，在激光诱导等离子体中，氧化钆的振动和旋转跃迁 A(1-0)、A(1-2) 和 A(2-1) 在天然氧化钆、156氧化钆和 158氧化钆的发射中表现出明显的差异。绝对值在 0.4-0.5 cm-1 范围内。除了具有足够的光谱分辨率之外，Demon HR 双梯度单色仪还证明了其在稀土元素同位素分析方面的灵敏度。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Spectrochimica Acta Part B: Atomic Spectroscopy 物理-光谱学

CiteScore

6.10

自引率

12.10%

发文量

173

审稿时长

81 days

期刊介绍： Spectrochimica Acta Part B: Atomic Spectroscopy, is intended for the rapid publication of both original work and reviews in the following fields: Atomic Emission (AES), Atomic Absorption (AAS) and Atomic Fluorescence (AFS) spectroscopy; Mass Spectrometry (MS) for inorganic analysis covering Spark Source (SS-MS), Inductively Coupled Plasma (ICP-MS), Glow Discharge (GD-MS), and Secondary Ion Mass Spectrometry (SIMS). Laser induced atomic spectroscopy for inorganic analysis, including non-linear optical laser spectroscopy, covering Laser Enhanced Ionization (LEI), Laser Induced Fluorescence (LIF), Resonance Ionization Spectroscopy (RIS) and Resonance Ionization Mass Spectrometry (RIMS); Laser Induced Breakdown Spectroscopy (LIBS); Cavity Ringdown Spectroscopy (CRDS), Laser Ablation Inductively Coupled Plasma Atomic Emission Spectroscopy (LA-ICP-AES) and Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS). X-ray spectrometry, X-ray Optics and Microanalysis, including X-ray fluorescence spectrometry (XRF) and related techniques, in particular Total-reflection X-ray Fluorescence Spectrometry (TXRF), and Synchrotron Radiation-excited Total reflection XRF (SR-TXRF). Manuscripts dealing with (i) fundamentals, (ii) methodology development, (iii)instrumentation, and (iv) applications, can be submitted for publication.