An iron-free nitrogenase? Computational estimation of the ability to bind/activate N2 in manganese and cobalt complexes

IF 2.2 4区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR
Rami Doukeh, Daniela Craciun, Maria Lehene, Adrian M. V. Branzanic, Alexandru Lupan, Radu Silaghi-Dumitrescu
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引用次数: 0

Abstract

Activation of N2 to ammonia occurs in nitrogenases at an unusual carbide-iron-sulfur active site. To deconvolute the factors that allow the nitrogenase Fe to bind N2, we have recently reported a de...
无铁氮化酶?锰和钴复合物结合/激活 N2 能力的计算估算
氮酶在一个不寻常的碳-铁-硫活性位点将N2活化为氨。为了解密氮酶铁与 N2 结合的因素,我们最近报告了一种脱碳-铁-硫活性位点。
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来源期刊
Journal of Coordination Chemistry
Journal of Coordination Chemistry 化学-无机化学与核化学
CiteScore
3.60
自引率
10.50%
发文量
171
审稿时长
3.2 months
期刊介绍: The Journal of Coordination Chemistry publishes the results of original investigations of coordination complexes, loosely defined as the interactions of organic or inorganic ligands with metal centres. Original investigations may involve syntheses, structures, physical and chemical properties, kinetics and mechanisms of reactions, calculations and applications of coordination compounds. The applications may involve bioinorganic, organometallic, catalytic, solid state/materials, coordination chemistry of nanostructured surfaces and medicinal studies. The Journal publishes original manuscripts, communications and reviews. Original manuscripts are expected to provide a clear contribution to the advance of coordination chemistry. Communications are short manuscripts with an urgency that requires rapid publication. Reviews are welcome in all areas of coordination chemistry and may focus on the metal, ligand or applications. Reviews of emerging areas of coordination chemistry should be developed fully from the basics, carefully relating the topic to the field in general. Reviews of well established subjects should collect developments from the literature and take a critical view of recent work.
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