Lindblad Relaxation of Multiple Quantum NMR Coherence in Two-Spin Systems

IF 1.1 4区 物理与天体物理 Q4 PHYSICS, ATOMIC, MOLECULAR & CHEMICAL
G. A. Bochkin, E. B. Fel’dman, E. I. Kuznetsova, S. G. Vasil’ev
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引用次数: 0

Abstract

The Lindblad equation for dissipative open systems is applied for an investigation of relaxation of multiple-quantum (MQ) NMR coherences in two-spin systems. We choose two examples of two-spin systems. One of them is the zigzag proton chain in a single crystal of hambergite in such an orientation that one of the two intra-chain dipolar coupling constants becomes zero. Then, the chain consists of well-isolated pairs of spins, with the spins of each pair coupled by the dipole–dipole interaction. The second example of a two-spin system is a single crystal of gypsum in which protons belong to water molecules. The MQ NMR dynamics with relaxation was investigated for different preparation times of the MQ NMR experiment.

Abstract Image

Abstract Image

双针系统中多重量子核磁共振相干的林德布拉德弛豫
我们将耗散开放系统的林德布拉德方程用于研究双自旋系统中多量子(MQ)核磁共振相干性的弛豫。我们选择了两个双自旋系统的例子。其中一个是汉贝格石单晶体中的人字形质子链,其取向使得链内两个双极耦合常数中的一个变为零。这样,质子链就由孤立的成对自旋组成,每对自旋通过偶极-偶极相互作用耦合在一起。双自旋系统的第二个例子是石膏单晶体,其中的质子属于水分子。研究了不同 MQ NMR 实验准备时间下的 MQ NMR 动态弛豫。
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来源期刊
Applied Magnetic Resonance
Applied Magnetic Resonance 物理-光谱学
CiteScore
1.90
自引率
10.00%
发文量
59
审稿时长
2.3 months
期刊介绍: Applied Magnetic Resonance provides an international forum for the application of magnetic resonance in physics, chemistry, biology, medicine, geochemistry, ecology, engineering, and related fields. The contents include articles with a strong emphasis on new applications, and on new experimental methods. Additional features include book reviews and Letters to the Editor.
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