Perspective on the description of viscoelastic flows via continuum elastic dumbbell models

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Evgeniy Boyko, Howard A. Stone
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引用次数: 0

Abstract

Non-Newtonian fluid mechanics and computational rheology widely exploit elastic dumbbell models such as Oldroyd-B and FENE-P for a continuum description of viscoelastic fluid flows. However, these constitutive equations fail to accurately capture some characteristics of realistic polymers, such as the steady extension in simple shear and extensional flows, thus questioning the ability of continuum-level modeling to predict the hydrodynamic behavior of viscoelastic fluids in more complex flows. Here, we present seven elastic dumbbell models, which include different microstructurally inspired terms, i.e., (i) the finite polymer extensibility, (ii) the conformation-dependent friction coefficient, and (iii) the conformation-dependent non-affine deformation. We provide the expressions for the steady dumbbell extension in shear and extensional flows and the corresponding viscosities for various elastic dumbbell models incorporating different microscopic features. We show the necessity of including these microscopic features in a constitutive equation to reproduce the experimentally observed polymer extension in shear and extensional flows, highlighting their potential significance in accurately modeling viscoelastic channel flow with mixed kinematics.

Abstract Image

通过连续弹性哑铃模型描述粘弹性流动的视角
非牛顿流体力学和计算流变学广泛利用弹性哑铃模型(如 Oldroyd-B 和 FENE-P)来连续描述粘弹性流体流动。然而,这些构成方程无法准确捕捉现实聚合物的某些特性,例如在简单剪切和伸展流动中的稳定伸展,从而质疑了连续级模型预测粘弹性流体在更复杂流动中的流体力学行为的能力。在此,我们提出了七个弹性哑铃模型,其中包括不同的微观结构启发项,即 (i) 有限聚合物延伸性、(ii) 与构象相关的摩擦系数和 (iii) 与构象相关的非非线性变形。我们为包含不同微观特征的各种弹性哑铃模型提供了剪切流和伸展流中哑铃稳定伸展的表达式以及相应的粘度。我们证明了在构成方程中包含这些微观特征对再现实验观察到的剪切流和延伸流中聚合物延伸的必要性,并强调了它们在精确模拟具有混合运动学的粘弹性通道流中的潜在意义。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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