Nanoplatelet Orientation and Young’s Modulus of Graphene/Phenoxy Nanocomposites

IF 2.3 4区 材料科学 Q3 MATERIALS SCIENCE, COMPOSITES
Han Lin, Prasad Potluri, William W. Sampson, Arthur N. Wilkinson
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Abstract

We report on the development of phenoxy-graphene nano-composite fibres for improving the toughness of thermoset composites. In this paper, a systematic experimental investigation into the underlying mechanisms of graphene nanoplatelets (GNP) reinforcement of phenoxy nanocomposite fibres prepared via melt spinning is provided. The analysis reveals a tangential orientation of GNP in the outer layer of the fibres, while such orientation is absent in the fibre core region. We show that the relative size of the fibre sheath depends on process variables and exhibits a linear relationship with the modulus of GNP obtained via theoretical analysis using simple rule of mixtures. This is because the area ratio (AR) is proportional to the orientation degree of GNP. This indicates that the enhancement of the Young’s modulus of fibres mainly originates from the increased AR of the fibre sheath layer where the orientation of GNP is more regular.

Abstract Image

石墨烯/苯氧基纳米复合材料的纳米小板取向和杨氏模量
我们报告了用于改善热固性复合材料韧性的苯氧基-石墨烯纳米复合纤维的开发情况。本文对通过熔融纺丝法制备的苯氧基纳米复合纤维的石墨烯纳米片(GNP)增强机理进行了系统的实验研究。分析表明,GNP 在纤维外层呈切向取向,而在纤维核心区域则没有这种取向。我们的研究表明,纤维鞘的相对尺寸取决于工艺变量,并与通过使用简单混合物规则进行理论分析获得的 GNP 模量呈线性关系。这是因为面积比 (AR) 与 GNP 的取向度成正比。这表明,纤维杨氏模量的提高主要源于 GNP 取向更规则的纤维鞘层 AR 的增加。
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来源期刊
Applied Composite Materials
Applied Composite Materials 工程技术-材料科学:复合
CiteScore
4.20
自引率
4.30%
发文量
81
审稿时长
1.6 months
期刊介绍: Applied Composite Materials is an international journal dedicated to the publication of original full-length papers, review articles and short communications of the highest quality that advance the development and application of engineering composite materials. Its articles identify problems that limit the performance and reliability of the composite material and composite part; and propose solutions that lead to innovation in design and the successful exploitation and commercialization of composite materials across the widest spectrum of engineering uses. The main focus is on the quantitative descriptions of material systems and processing routes. Coverage includes management of time-dependent changes in microscopic and macroscopic structure and its exploitation from the material''s conception through to its eventual obsolescence.
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