Recrystallization and grain growth activation energies in a hybrid magnesium material fabricated by high-pressure torsion

IF 3.1 2区 化学 Q2 CHEMISTRY, ANALYTICAL
Hiba Azzeddine , Marie-Noëlle Avettand-Fènoël , Piotr Bazarnik , Thierry Baudin , Yi Huang , Terence G. Langdon
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Abstract

The recrystallization and grain growth activation energies of the hybrid AZ31/Mg-0.6Gd (wt.%) alloy were calculated using differential scanning calorimetry analyses and scanning electron microscopy, respectively, after fabricating by high-pressure torsion up to 20 turns and then subjecting to an isochronal annealing treatment from 423 to 723 K for 1 h. The DSC results show one exothermic peak belonging to the static recrystallization of the AZ31 region with an activation energy of 112 ± 10 kJ/mol. The grain growth kinetics for the AZ31 and Mg-0.6Gd regions were described by the Arrhenius equation. The calculation with a grain growth exponent equal to 4 gave values for the activation energies in both the AZ31 (146.2 ± 8.4 kJ/mol) and Mg-0.6Gd (90.9 ± 13.5 kJ/mol) regions. The present results reveal the heterogeneity of the thermal stability of the AZ31/Mg-0.6Gd hybrid material.

Abstract Image

高压扭转法制造的混合镁材料中的再结晶和晶粒生长活化能
利用差示扫描量热分析和扫描电子显微镜,分别计算了高压扭转制造 20 圈,然后在 423 至 723 K 等温退火处理 1 小时后,混合 AZ31/Mg-0.6Gd (wt.%) 合金的再结晶和晶粒生长活化能。AZ31 和 Mg-0.6Gd 区域的晶粒生长动力学由阿伦尼乌斯方程描述。晶粒生长指数等于 4 的计算得出了 AZ31(146.2 ± 8.4 kJ/mol)和 Mg-0.6Gd (90.9 ± 13.5 kJ/mol)区域的活化能值。本研究结果揭示了 AZ31/Mg-0.6Gd 混合材料热稳定性的异质性。
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来源期刊
Thermochimica Acta
Thermochimica Acta 化学-分析化学
CiteScore
6.50
自引率
8.60%
发文量
210
审稿时长
40 days
期刊介绍: Thermochimica Acta publishes original research contributions covering all aspects of thermoanalytical and calorimetric methods and their application to experimental chemistry, physics, biology and engineering. The journal aims to span the whole range from fundamental research to practical application. The journal focuses on the research that advances physical and analytical science of thermal phenomena. Therefore, the manuscripts are expected to provide important insights into the thermal phenomena studied or to propose significant improvements of analytical or computational techniques employed in thermal studies. Manuscripts that report the results of routine thermal measurements are not suitable for publication in Thermochimica Acta. The journal particularly welcomes papers from newly emerging areas as well as from the traditional strength areas: - New and improved instrumentation and methods - Thermal properties and behavior of materials - Kinetics of thermally stimulated processes
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