Jiali Chen, Yuying Fu, Shoujie Shen, Qiaoyun Liu, Jinjian Liu
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引用次数: 0
Abstract
Two new Zn(II) metal-organic frameworks (MOFs) {[Zn(Bpybc)0.5 (m-BDC)(H2O)]·2H2O}n (1) and {[Zn(H2Bpybc)(BTEC)(H2O)2]·H2O}n (2) have been successfully synthesized, where 1,1′-bis(4-carboxybenzyl)-4,4′-bipyridinium dichloride (H2BpybcCl2) is used to react as the predesigned ligand with two kinds of aromatic carboxylic acids (1,3-benzenedicarboxylic acid = m-H2BDC, 1,2,4,5-benzenetetracarboxylic acid = H4BTEC) as the secondary building linkers. Both two compounds own two-dimensional (2D) layered structures. In addition, compounds 1 and 2 display reversible photochromism, which is associated with the generation of free radicals via photoinduced electron transfer. Simultaneously, the photomodulated fluorescent properties and their potential applications in ink-less and erasable printing were also studied.
期刊介绍:
Dyes and Pigments covers the scientific and technical aspects of the chemistry and physics of dyes, pigments and their intermediates. Emphasis is placed on the properties of the colouring matters themselves rather than on their applications or the system in which they may be applied.
Thus the journal accepts research and review papers on the synthesis of dyes, pigments and intermediates, their physical or chemical properties, e.g. spectroscopic, surface, solution or solid state characteristics, the physical aspects of their preparation, e.g. precipitation, nucleation and growth, crystal formation, liquid crystalline characteristics, their photochemical, ecological or biological properties and the relationship between colour and chemical constitution. However, papers are considered which deal with the more fundamental aspects of colourant application and of the interactions of colourants with substrates or media.
The journal will interest a wide variety of workers in a range of disciplines whose work involves dyes, pigments and their intermediates, and provides a platform for investigators with common interests but diverse fields of activity such as cosmetics, reprographics, dye and pigment synthesis, medical research, polymers, etc.