Isomerization of maltose to maltulose under microwave heating using uncalcined scallop shell powder

Abstract

Uncalcined scallop shell powder, consisting mainly of calcium carbonate, and an aqueous maltose solution were placed in a pressure-resistant vessel and heated in a domestic microwave oven to isomerize maltose to maltulose. When a maltose solution (50 mL) was heated at a power of 700 W, a high maltulose yield of approximately 30 % was achieved in as short a time as 105 s. As the reaction progressed, the shell powder dissolved and neutralized acidic by-products to suppress the decrease in pH, keeping the pH above 7, where the isomerization by Lobry de Bruyn-Alberda van Ekenstein transformation proceeded. The average selectivity for isomerization of maltose to maltulose under various reaction conditions was 0.822. This would be because the shell powder kept the pH of the reaction solution in the range of 7–9 and suppressed the progression of side reactions. The coloration of the reaction solution increased rapidly when the yield of maltulose approached its maximum value. This indicated that if the reaction were to be stopped when the yield of maltulose was close to its maximum value, a high yield of maltulose solution with low coloration could be obtained.